Aliphatic compound

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Acyclic aliphatic/non-aromatic compound (butane)
Cyclic aliphatic/non-aromatic compound (cyclobutane)

In organic chemistry, hydrocarbons (compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (/ˌælɪˈfætɪk/; G. aleiphar, fat, oil). Aliphatic compounds can be saturated (in which all the C-C bonds are single requiring the structure to be completed, or 'saturated', by hydrogen) like hexane, or unsaturated, like hexene and hexyne. Open-chain compounds, whether straight or branched, and which contain no rings of any type, are always aliphatic. Cyclic compounds can be aliphatic if they are not aromatic.[1]

Structure

Aliphatic compounds can be

aromatic amines
.

The least complex aliphatic compound is methane (CH4).

Properties

Most aliphatic compounds are

ethyne (acetylene) in welding
.

Examples of aliphatic compounds

The most important aliphatic compounds are:

  • n-, iso- and cyclo-alkanes (saturated hydrocarbons)
  • n-, iso- and cyclo-alkenes and -alkynes (unsaturated hydrocarbons).

Important examples of low-molecular aliphatic compounds can be found in the list below (sorted by the number of carbon-atoms):

Formula Name Structural formula Chemical classification
CH4 Methane Alkane
C2H2 Acetylene Alkyne
C2H4 Ethylene Alkene
C2H6 Ethane Alkane
C3H4 Propyne Alkyne
C3H6
Propene
Alkene
C3H8 Propane Alkane
C4H6 1,2-Butadiene Diene
C4H6 1-Butyne Alkyne
C4H8 1-Butene Alkene
C4H10 Butane Alkane
C6H10 Cyclohexene Cycloalkene
C5H12
n-pentane
Alkane
C7H14 Cycloheptane Cycloalkane
C7H14 Methylcyclohexane Cyclohexane
C8H8 Cubane Prismane, Platonic hydrocarbon
C9H20 Nonane Alkane
C10H12 Dicyclopentadiene Diene, Cycloalkene
C10H16 Phellandrene Terpene, Diene, Cycloalkene
C10H16
α-Terpinene
Terpene, Diene, Cycloalkene
C10H16 Limonene Terpene, Diene, Cycloalkene
C11H24 Undecane Alkane
C30H50 Squalene Terpene, Polyene
C2nH4n Polyethylene Alkane

References