Ambergris

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Ambergris in dried form

Ambergris (

astringency.[2]

Ambergris has been highly valued by perfume makers as a fixative that allows the scent to last much longer, although it has been mostly replaced by synthetic ambroxide.[3] Dogs are attracted to the smell of ambergris and are sometimes used by ambergris searchers.[4]

Etymology

The English word amber derives from the Arabic word ʿanbar (عنبر;[5] ultimately from Middle Persian ambar,[6] also ambergris), via Middle Latin ambar and Middle French ambre. The word "amber", in its sense of "ambergris", was adopted in Middle English in the 14th century.[5]

The word "ambergris" comes from the Old French ambre gris or "grey amber".[7][8] The addition of "grey" came about when, in the Romance languages, the sense of the word "amber" was extended to Baltic amber (fossil resin), as white or yellow amber (ambre jaune), from as early as the late 13th century.[5] This fossilized resin subsequently became the dominant (and now exclusive) sense of "amber", leaving "ambergris" as the word for the whale secretion.

The archaic alternate spelling "ambergrease" arose as an eggcorn from the phonetic pronunciation of "ambergris," encouraged by the substance's waxy texture.[9]

Formation

Ambergris is formed from a secretion of the

sperm whales.[7] Because the beaks of giant squids
have been discovered within lumps of ambergris, scientists have theorized that the substance is produced by the whale's gastrointestinal tract to ease the passage of hard, sharp objects that it may have eaten.

Ambergris is passed like fecal matter. It is speculated that an ambergris mass too large to be passed through the intestines is expelled via the mouth, but this remains under debate.[10] Another theory states that an ambergris mass is formed when the colon of a whale is enlarged by a blockage from intestinal worms and cephalopod parts resulting in the death of the whale and the mass being excreted into the sea.[11] Ambergris takes years to form. Christopher Kemp, the author of Floating Gold: A Natural (and Unnatural) History of Ambergris, says that it is only produced by sperm whales, and only by an estimated one percent of them. Ambergris is rare; once expelled by a whale, it often floats for years before making landfall.[12] The slim chances of finding ambergris and the legal ambiguity involved led perfume makers away from ambergris, and led chemists on a quest to find viable alternatives.[13]

Ambergris is found primarily in the

The Maldives; China; Japan; India; Australia; New Zealand; and the Molucca Islands. Most commercially collected ambergris comes from the Bahamas in the Atlantic, particularly New Providence. In 2021, fishermen found a 127 kg (280-pound) piece of ambergris off the coast of Yemen, valued at US$1.5 million.[14] Fossilised ambergris from 1.75 million years ago has also been found.[15]

Physical properties

Ambergris is found in lumps of various shapes and sizes, usually weighing from 15 grams (12 ounce) to 50 kilograms (110 pounds) or more.

specific gravity ranging from 0.780 to 0.926 (meaning it floats in water). It melts at about 62 °C (144 °F) to a fatty, yellow resinous liquid; and at 100 °C (212 °F) it is volatilised into a white vapor. It is soluble in ether, and in volatile and fixed oils.[7]

Chemical properties

Ambergris is relatively nonreactive to acid. White crystals of a terpenoid known as ambrein, discovered by Leopold Ružička and Fernand Lardon in 1946,[16][17][18] can be separated from ambergris by heating raw ambergris in alcohol, then allowing the resulting solution to cool. Breakdown of the relatively scentless ambrein through oxidation produces ambroxide and ambrinol, the main odor components of ambergris.

  • Ambrein
    Ambrein
  • Ambroxide
    Ambroxide
  • Ambrinol
    Ambrinol

Ambroxide is now produced synthetically and used extensively in the perfume industry.[19]

Applications

Ambergris has been mostly known for its use in creating perfume and fragrance much like musk. Perfumes based on ambergris still exist.[20] Ambergris has historically been used in food and drink. A serving of eggs and ambergris was reportedly King Charles II of England's favorite dish.[21] A recipe for Rum Shrub liqueur from the mid 19th century called for a thread of ambergris to be added to rum, almonds, cloves, cassia, and the peel of oranges in making a cocktail from The English and Australian Cookery Book.[22] It has been used as a flavoring agent in Turkish coffee[23] and in hot chocolate in 18th century Europe.[24] The substance is considered an aphrodisiac in some cultures.[25]

cause of plague
.

During the

medication for headaches, colds, epilepsy, and other ailments.[27]

Legality

From the 18th to the mid-19th century, the whaling industry prospered. By some reports, nearly 50,000 whales, including sperm whales, were killed each year. Throughout the 19th century, "millions of whales were killed for their oil, whalebone, and ambergris" to fuel profits, and they soon became endangered as a species as a result.[28] Due to studies showing that the whale populations were being threatened, the International Whaling Commission instituted a moratorium on commercial whaling in 1982. Although ambergris is not harvested from whales, many countries also ban the trade of ambergris as part of the more general ban on the hunting and exploitation of whales.

Urine, faeces, and ambergris (that has been naturally excreted by a sperm whale) are waste products not considered parts or derivatives of a CITES species and are therefore not covered by the provisions of the convention.[29]

Countries where ambergris trade is illegal include:

Countries where trade of ambergris is legal include:

References

  1. ^ "Ambergris". Britannica. Retrieved 31 January 2013.
  2. .
  3. ^ Panten, J. and Surburg, H. 2016. Flavors and Fragrances, 3. Aromatic and Heterocyclic Compounds. Ullmann's Encyclopedia of Industrial Chemistry. 1–45.
  4. ^ "Jovoy Paris 'Designed' for Fascinating Olfactory Experiences". Ikon London Magazine. October 2017. Retrieved October 12, 2017.
  5. ^ a b c "amber | Etymology, origin and meaning of amber by etymonline". Online Etymology Dictionary. Retrieved 2023-01-11.
  6. OCLC 1124409881. Archived from the original (PDF) on 3 December 2012. on Google Books
  7. ^ a b c d Chisholm, Hugh, ed. (1911). "Ambergris" . Encyclopædia Britannica. Vol. 1 (11th ed.). Cambridge University Press. p. 794.
  8. ^ Wedgwood, Hensleigh (1855). "On False Etymologies". Transactions of the Philological Society (6): 66.
  9. ^ "ambergris". Oxford English Dictionary (Online ed.). Oxford University Press. December 2022. Retrieved 28 February 2023. (Subscription or participating institution membership required.)
  10. .
  11. .
  12. .
  13. ^ Daley, Jason (14 April 2016). "Your High-End Perfume Is Likely Part Whale Mucus". Smithsonian. Retrieved 6 August 2018.
  14. ^ "A group of fishermen netted a $1.5 million whale-vomit windfall after dredging up a 127 280-pound hunk of the stuff". Business Insider.
  15. .
  16. .
  17. .
  18. .
  19. ^ "Ambrox/Ambroxan: a Modern Fascination on an Elegant Material". Perfume Shrine. 5 November 2010. Retrieved 31 January 2013.
  20. ^ Spitznagel, Eric (January 12, 2012). "Ambergris, Treasure of the Deep". Bloomberg Businessweek. Archived from the original on January 14, 2012. Retrieved 31 January 2013.
  21. Lord Macaulay (1848). "IV"
    . The History of England from the Accession of James II. Vol. 1. Harper. p. 222.
  22. ^ Abbott, Edward (1864). The English and Australian Cookery Book. p. 272 (at the top).
  23. ^ "The starting point of Turkish coffee: Istanbul's historic coffeehouses". The Istanbul Guide. Archived from the original on 18 October 2020. Retrieved 26 October 2018.
  24. ^ Green, Matthew (March 11, 2017). "How the decadence and depravity of London's 18th century elite was fuelled by hot chocolate". The Daily Telegraph. Archived from the original on 2022-01-12. Retrieved July 15, 2017.
  25. OCLC 787843317
    .
  26. .
  27. ^ a b Graber, Cynthia (April 26, 2007). "Strange but True: Whale Waste Is Extremely Valuable". Scientific American. Retrieved 31 January 2013.
  28. .
  29. ^ CITES CoP16 Com. II Rec. 2 (Rev. 1), Convention on International Trade in Endangered Species of Wild Fauna and Flora, Sixteenth meeting of the Conference of the Parties Bangkok (Thailand), 3–14 March 2013 Summary record of the second session of Committee II
  30. ^ "Whale and Dolphin permits – Ambergris". Environment.gov.au. 1979-06-28. Retrieved 2014-03-13.
  31. ^ "Ambergris, Treasure of the Deep". Businessweek. 2012-01-12. Archived from the original on January 14, 2012. Retrieved 2014-03-13.
  32. ^ a b c d "Ambergris: lucky, lucrative and legal?". 10 September 2015.

Further reading

External links