Antimony trioxide

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Antimony(III) oxide
Antimony(III) oxide
Names
IUPAC name
Antimony(III) oxide
Other names
Antimony sesquioxide
Antimonous oxide
Flowers of Antimony
Identifiers
3D model (
JSmol
)
ChemSpider
ECHA InfoCard
100.013.796 Edit this at Wikidata
EC Number
  • 215-474-6
KEGG
RTECS number
  • CC5650000
UNII
  • InChI=1S/3O.2Sb checkY
    Key: ADCOVFLJGNWWNZ-UHFFFAOYSA-N checkY
  • InChI=1/3O.2Sb/rO3Sb2/c1-4-3-5-2
    Key: ADCOVFLJGNWWNZ-VTKDZCJOAA
  • O=[Sb]O[Sb]=O
Properties
Sb2O3
Molar mass 291.518 g/mol
Appearance white solid
Odor odorless
Density 5.2 g/cm3, α-form
5.67 g/cm3 β-form
Melting point 656 °C (1,213 °F; 929 K)
Boiling point 1,425 °C (2,597 °F; 1,698 K) (sublimes)
370±37 µg/L between 20.8 °C and 22.9 °C
Solubility soluble in acid
−69.4×10−6 cm3/mol
2.087, α-form
2.35, β-form
Structure
orthorhombic
(β) > 570 °C
pyramidal
zero
Hazards
GHS labelling:
GHS08: Health hazard[1]
Warning[1]
H351[1]
P281[1]
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Lethal dose or concentration (LD, LC):
7000 mg/kg, oral (rat)
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.5 mg/m3 (as Sb)[2]
REL (Recommended)
TWA 0.5 mg/m3 (as Sb)[2]
Related compounds
Other anions
Antimony trisulfide
Antimony triselenide
Antimony telluride
Other cations
Bismuth trioxide
Related compounds
Diantimony tetraoxide
Antimony pentoxide
Supplementary data page
Antimony trioxide (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Antimony(III) oxide is the inorganic compound with the formula Sb2O3. It is the most important commercial compound of antimony. It is found in nature as the minerals valentinite and senarmontite.[3] Like most polymeric oxides, Sb2O3 dissolves in aqueous solutions with hydrolysis. A mixed arsenic-antimony oxide occurs in nature as the very rare mineral stibioclaudetite.[4][5]

Production and properties

Global production of antimony(III) oxide in 2012 was 130,000 tonnes, an increase from 112,600 tonnes in 2002. China produces the largest share followed by US/Mexico, Europe, Japan and South Africa and other countries (2%).[6]

As of 2010, antimony(III) oxide was produced at four sites in the EU. It is produced via two routes, re-volatilizing of crude antimony(III) oxide and by oxidation of antimony metal. Oxidation of antimony metal dominates in Europe. Several processes for the production of crude antimony(III) oxide or metallic antimony from virgin material. The choice of process depends on the composition of the ore and other factors. Typical steps include mining, crushing and grinding of ore, sometimes followed by froth flotation and separation of the metal using pyrometallurgical processes (smelting or roasting) or in a few cases (e.g. when the ore is rich in precious metals) by hydrometallurgical processes. These steps do not take place in the EU but closer to the mining location.

Re-volatilizing of crude antimony(III) oxide

Step 1) Crude stibnite is oxidized to crude antimony(III) oxide using furnaces operating at approximately 500 to 1,000 °C. The reaction is the following:

2 Sb2S3 + 9 O2 → 2 Sb2O3 + 6 SO2

Step 2) The crude antimony(III) oxide is purified by sublimation.

Oxidation of antimony metal

Antimony metal is oxidized to antimony(III) oxide in furnaces. The reaction is exothermic. Antimony(III) oxide is formed through sublimation and recovered in bag filters. The size of the formed particles is controlled by process conditions in furnace and gas flow. The reaction can be schematically described by:

4 Sb + 3 O2 → 2 Sb2O3

Properties

Antimony(III) oxide is an

antimony(V) oxide.[8]

When heated with

potassium antimony tartrate, KSb(OH)2·C4H2O6, is formed.[8]

Structure

The structure of Sb2O3 depends on the temperature of the sample. Dimeric Sb4O6 is the high temperature (1560 °C) gas.

orthorhombic, consisting of pairs of -Sb-O-Sb-O- chains that are linked by oxide bridges between the Sb centers. This form exists in nature as the mineral valentinite.[11]

Sb4O6 senarmontite valentinite

Uses

The annual consumption of antimony(III) oxide in the United States and Europe is approximately 10,000 and 25,000 tonnes, respectively. The main application is as flame retardant synergist in combination with halogenated materials. The combination of the halides and the antimony is key to the flame-retardant action for polymers, helping to form less flammable chars. Such flame retardants are found in electrical apparatuses, textiles, leather, and coatings.[13]

Other applications:

Safety

Antimony(III) oxide has suspected carcinogenic potential for humans.

US Department of Health and Human Services categorised antimony(III) oxide as carcinogenic.[15]

References

  1. ^ a b c d Record of Antimony trioxide in the GESTIS Substance Database of the Institute for Occupational Safety and Health, accessed on 23 August 2017.
  2. ^ a b NIOSH Pocket Guide to Chemical Hazards. "#0036". National Institute for Occupational Safety and Health (NIOSH).
  3. .
  4. ^ "Stibioclaudetite".
  5. ^ "List of Minerals". 21 March 2011.
  6. ^ European Union Risk Assessment Report: DIANTIMONY TRIOXIDE (draft) (PDF) (Report). Sweden. November 2008. CAS No: 1309-64-4; EINECS No: 215-175-0. Archived from the original (PDF) on 2014-01-06.
  7. .
  8. ^ .
  9. .
  10. .
  11. ^ .
  12. .
  13. ^ .
  14. ^ Newton, P. E.; Schroeder, R. E.; Zwick, L.; Serex, T. (2004). "Inhalation Developmental Toxicity Studies In Rats With Antimony(III) oxide (Sb2O3)". Toxicologist. 78 (1–S): 38.
  15. ^ "15th Report on Carcinogens". National Toxicology Program. Retrieved 2023-06-15.

Further reading

  • Institut national de recherche et de sécurité (INRS), Fiche toxicologique nº 198 : Trioxyde de diantimoine, 1992.
  • The Oxide Handbook, G.V. Samsonov, 1981, 2nd ed. IFI/Plenum,

External links