Carbide chloride
Carbide chlorides are
cluster compounds
, in which metal atoms encase a carbon core, with chlorine atoms surrounding the cluster. The chlorine may be shared between clusters to form polymers or layers. Most carbide chloride compounds contain rare earth elements. Some are known from group 4 elements. The hexatungsten carbon cluster can be oxidised and reduced, and so have different numbers of chlorine atoms included.
The carbide chlorides are a subset of the halide carbides, with related compounds including the
carbide iodides
. Cluster compounds similar to these carbides, may instead replace carbon with boron, hydrogen, nitrogen or phosphorus.
List
formula | system | space group | unit cell | volume | density | comment | reference |
---|---|---|---|---|---|---|---|
Ca3C3Cl2 | orthorhombic | Cmcm | a=3.876, b=13.524, c=11.653 | 2.47 | red | [1] | |
Sc2CCl2 | P3m1 | a=3.39977 c=8.858 | 3.24 | black | [2] | ||
Sc5CCl8 | monoclinic | C12/m1 | a=17.8 b=3.5259 c=12.052 β=130.11 | 2.99 | [2] | ||
Sc7C2Cl10 | monoclinic | C12/m1 | a=18.62 b=11.81 β=99.81 | 3.04 | ruby red; moisture sensitive | [3][2] | |
Ti6CCl14 | orthorhombic | Cmce | a=12.4592 b=12.2458 c=10.9576 | 2.93 | black | [2] | |
YCCl | C12/m1 | a=6.82 b=3.713 c=9.327 β=94.75 | 3.85 | [2] | |||
Y2C0.7Cl2 | P3m1 | a=3.7022 c=9.195 | 3.91 | silvery grey | [2] | ||
Zr6CCl14 | orthorhombic | Cmce | a=14.091 b=12.595 c=11.506 | 3.43 | brown red | [4][2] | |
KZr6CCl15 | orthorhombic | Pnma | a=18.489 b=13.909 c=9.690 Z=4 | 2492 | dark red; Zr6C clusters | [5] | |
Rb4Zr6CCl18 | C2/m | a=10.460 b=17.239 c=9.721 β=115.05 Z=2 | [6] | ||||
Rb[(Zr6C)Cl15] | orthorhombic | Pnma | a=18.484,b= 18.962,c=9.708 Z= 4 | 2505.4 | 3.12 | dark red-brown | [7] |
Cs4[Sc6C]Cl13 | tetragonal | I41/amd | a = 15.405, c = 10.179 Z=4 | green black | [8] | ||
Cs[(Zr6C)Cl15] | orthorhombic | Pnma | a = 18.513 b = 13.916 c = 9.6383 Z=4 | 2483.1 | dark red | [9] | |
La2CCl | R3m | a=3.878 c=16.91 | 5.74 | coppery red | [10] | ||
La2C2Cl | monoclinic | C12/c1 | a=14.77 b=4.187 c=6.802 β=101.5 | 5.44 | gold | [11][10] | |
La3C3Cl2 | monoclinic | C12/c1 | a=7.771 b=12.962 c=6.91 β=104.3 | 5.16 | gold | [10] | |
La4C2Cl5 | orthorhombic | Immm | a=3.92 b=7.945 c=19.297 | 4.67 | black | [10] | |
La4C5Cl2 | monoclinic | C12/m1 | a=22.57 b=3.91 c=1.019 β=95.69 | 5.07 | gold | [10] | |
La5C2Cl9 | triclinic | P1 | a=8.645 b=8.706 c=11.925 α=84.97° β=85.78° γ=61.31° | 4.40 | red | [10] | |
La6(C2)3Cl4 | monoclinic | P21/c | a = 7.770, b = 12.962, c = 6.910 and β = 104.30° Z=2 | 674.4 | 5.158 | gold; sheets of octahedra | [12] |
La8C8Cl5 | monoclinic | P121/c1 | a=7.756 b=16.951 c=6.878 β=104.2 | 5.24 | gold | [11][10] | |
La8(C2)5Cl4 | monoclinic | C2/m | a = 22.570, b = 3.9300, c = 10.190 β = 95.69° Z=2 | 899.4 | 5.071 | gold | [12] |
La11C11Cl7 | monoclinic | P121/c1 | a=7.77 b=47.038 c=6.901 β=104.28 | 5.19 | gold | [10] | |
La14C14Cl9 | monoclinic | P1C1 | a=7.775 b=2.9963 c=6.895 β=104.21 | 5.19 | gold | [11][10] | |
La20C20Cl13 | monoclinic | P121/c1 | a=7.762 b=42.941 c=6.903 β=104.26 | 5.18 | black | [11][10] | |
La36C36Cl23 | monoclinic | P121/c1 | a=7.764 b=77.055 c=6.897 β=104.26 | 5.18 | grey | [11][10] | |
K[La5(C2)]Cl10 | monoclinic | P21/c | a=8.5632, b=15.074, 17.115 β=119.74 Z=4 | 1918.3 | 3.85 | light red | [13] |
Ce2C2Cl | monoclinic | C12/c1 | a=14.573, b=4.129, c=6.696, β=101.37 | 5.71 | gold | [1] | |
Ce2(C2)2Cl | monoclinic | C2/c | a = 14.573, b = 4.129, c = 6.696, β = 101.37 ° | [14] | |||
Ce3CCl5 | monoclinic | C12/c1 | a=13.899, b=8.71, c=15.765, β=98.22 | 4.29 | orange | [1] | |
Ce4CCl8 | monoclinic | P1C1 | a=13.538, b=10.487, c=22.845, β=126.31 | 4.35 | black | [10][15] | |
Ce5C2Cl9 | triclinic | P1 | a=8.57, b=8.627, c=11.869, α=84.8, β=85.5, γ=61.29 | red | [1] | ||
Ce6Cl10C2 | monoclinic | C12/c1 | a= 13.899,b= 8.710,c= 15.765,β= 98.22° Z=4 | 1888.9 | [16] | ||
Ce8C8Cl5 | monoclinic | P121/c1 | a=7.669, b=16.784, c=6.798, β=104.05 | 5.46 | gold | [11][1] | |
Ce18(C2)9Cl11 | triclinic | P1 | a = 6.771, b = 7.657, c = 18.98,α = 88.90 °, β = 80.32 °, γ = 76.09 ° | [14] | |||
Ce26(C2)13Cl16 | monoclinic | P21/c | a = 7.664, b = 54.25, c = 6.796, β = 103.98 ° | [14] | |||
K[Ce5(C2)]Cl10 | monoclinic | P21/c | a=8.4739, b=15.017, c=1639 β=119.76 Z=4 | 1871.2 | 3.97 | red | [13] |
Pr3CCl5 | monoclinic | C12/c1 | a=13.867 b=8.638 c=15.69 β=97.67 | 4.37 | yellow | [2] | |
Pr4C2Cl5 | orthorhombic | Immm | a=3.848 b=7.759 c=17.01 | 5.00 | black | [2] | |
Pr5C2Cl9 | triclinic | P1 | a=8.526 b=8.592 c=11.821 α=84.77 β=85.42 γ=61.26 | 4.61 | brown red | [2] | |
Pr6C2Cl10 | monoclinic | C2/c | a = 13.687, b = 8.638, c = 15.690, β = 97.67° | yellow to green | [17] | ||
Pr8C8Cl5 | monoclinic | C121/c1 | a=7.617 b=16.689 c=6.769 β=103.94 | 5.57 | gold | [2] | |
Pr11C11Cl7 | monoclinic | P121/c1 | a=7.612 b=6.127 c=6.761 β=103.92 | 5.56 | gold | [2] | |
Pr14C14Cl9 | monoclinic | P1c1 | a=7.611 b=29.392 c=6.764 β=103.9 | 5.56 | gold | [2] | |
K{Pr5(C2)}Cl10 | hexagonal | P63/m | a=8.426 c=14.894 Z=2 | 915.9 | dark red | [18] | |
Rb{Pr5(C2)}Cl10 | hexagonal | P63/m | a=8.4499, c=14.976 Z=2 | 926 | 4.19 | red; trigonal bipyrmamid of Pr containing a C2 unit | [19] |
Rb[Nd5(C2)]Cl10 | hexagonal | a=08.398, c=14.88 | 4.33 | dark red | [13] | ||
Gd2C2Cl | P3m | a=3.6902, c=20.308 | [10] | ||||
Gd2C2Cl2 | monoclinic | P3m1 | a=3.7633, c=9.4593 | 5.69 | black; contains C24− | [4][10] | |
Gd3CCl3 | cubic | I4132 | a=10.734 | 6.34 | [10] | ||
Gd4C2Cl3 | orthorhombic | Pnma | a=10.596, b=3.684, c=19.627 | 6.58 | bronze | [10][20] | |
Gd5C2Cl9 | monoclinic | P121/c1 | a=9.182, b=16.12, c=12.886, β=119.86 | 4.54 | black | [10] | |
Gd5C6Cl3 | monoclinic | C12/m1 | 2.1507,0.37193,1.5331,90,123.34 | 6.25 | bronze | [10] | |
Gd6C3Cl5 | monoclinic | C12/m1 | a=16.688,b=3.6969,c=12.824, β=128.26 | 6.18 | grey | [10] | |
Gd10C4Cl17 | triclinic | P1 | a=8.498, b=9.174, c=11.462, α=104.56, β=95.98, γ=111.35 | 4.70 | black; contains C24− | [4][10] | |
Gd10C4Cl18 | triclinic | P1 | a = 8.498, b = 9.174, c = 11.462, α = 104.56°, β = 95.98°, γ = 111.35°, Z = 1 | contains C24− | [21][4] | ||
[Gd4(C2)](Cl, I)6 | tetragonal | P4/mbm | a = 13.475, c = 12.125, Z = 2 | black | [22] | ||
Rb2[Gd10(C2)2]Cl19 | orthorhombic | a=1.2228, b=2.2347, c=1.3896 | 4.31 | black | [23] | ||
Cs2[Gd10(C2)2]Cl19 | orthorhombic | a=1.2344, b=2.2434, c=1.3924 | 4.41 | black | [23] | ||
Cs3[Tb10(C2)2]Cl21 | monoclinic | C2/c | Z = 4; a = 23.187; b = 12.458; c = 15.02; β = 98.13° | black | [24] | ||
Lu2CCl2 | R3m | a=3.6017, c=27.16 | 7.07 | brown | [10] | ||
Lu2CCl2 | P3m1 | a= 3.5972, c=9.0925 | 7.05 | [10] | |||
Cs2Lu[Lu6C]Cl18 | R3 | a = 9.817, c = 27.232, Z = 3 | [25] | ||||
Hf6CCl14 | orthorhombic | Cmce | a=13.938, b=12.498, c=11.399 | 5.28 | [10] | ||
W2CCl8 | orthorhombic | Pbca | a=11.96 b=12.156 c=10.9576 | 2.83 | black | [2] | |
W6CCl15 | monoclinic | C121/c1 | a=9.8831 b=11.8945 c=17.867 β =107.883 | 5.47 | black | [2] | |
W6CCl16 | orthorhombic | Pnma | a=16.637 b=12.958 c=9.797 | 5.29 | black | [2] | |
W6CCl18 | P62c | a=8.923 c=17.503 | 4.82 | black | [2] | ||
W30C2(Cl,Br)68 | triclinic | P1 | a = 12.003, b = 14.862, c = 15.792, α = 88.75°, β = 68.85°, γ = 71.19° Z=1 | 2472.9 | black | [26] | |
Li[W6CCl18] | hexagonal | P63/m | a = 8.8648, c = 17.490 Z=2 | 1188.2 | black | [27][28] | |
(Bu4N)[W6CCl18] | [29] | ||||||
(Me4N)2[W6CCl18] | [28] | ||||||
(Bu4N)2[W6CCl18] | [29] | ||||||
(Bu4N)3[W6CCl18] | [29] | ||||||
Na[W6CCl18] | hexagonal | P63/m | a=8.9592 c=17.5226 Z=2 | 1188.2 | [28] | ||
Ca[W6CCl18] | hexagonal | P63/m | a=8.9384 c=17.6526 Z=2 | 1220.4 | [28] | ||
Cu[W6CCl18] | triclinic | P1 | a=8.89 b=8.929 c=17.669 α=81.85 β=80.78 γ=60.39 Z=2 | 1200.7 | 5.025 | black | [30] |
Cu(C2H6OS)6[W6CCl18] | monoclinic | C2/c | a=17.333 b=16.011 c=18.082 β=94.61 Z=4 | 5001.7 | 3.035 | dark brown | [30] |
Cu(C2H6OS)4[W6CCl18]2 | triclinic | P1 | a=9.47 b=12.630 c=13.634 α=104.69° β=90.16° γ=92.99° Z=1 | 1575.2 | 4.095 | dark violet | [30] |
Ag[W6CCl18] | hexagonal | P63/m | a=8.874 c=17.58 Z=2 | 1199 | [28] | ||
Cs[W6CCl18]·CH3OH | orthorhombic | P212121 | a = 9.6957, b = 14.046, c = 20.238 Z=4 | 4.623 | black; W in trigonal prism around C | [27] |
References
- ^ ISBN 978-3-11-031174-7.
- ^ ISBN 978-3-11-031174-7.
- .
- ^ ISSN 0020-1669.
- ISSN 0002-7863.
- ISSN 0020-1669.
- S2CID 197327959.
- ISSN 0044-2313.
- PMID 16456264.
- ^ ISBN 978-3-11-031174-7.
- ^ .
- ^ .
- ^ ISSN 0044-2313.
- ^ .
- .
- S2CID 93416923.
- .
- ISSN 0044-2313.
- ISSN 0570-0833.
- ISSN 0044-2313.
- ISSN 0044-2313.
- ISSN 0044-2313.
- ^ .
- ISSN 0044-2313.
- ISSN 0044-2313.
- PMID 20521794.
- ^ .
- ^ .
- ^ PMID 13129326.
- ^ .