Chromium(II) oxide
Names | |
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IUPAC name
chromium(II) oxide
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Identifiers | |
PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
CrO | |
Molar mass | 67.996 g/mol |
Appearance | black |
Melting point | 300 °C (572 °F; 573 K) (decomposes) |
Structure | |
cubic, cF8 | |
Fm3m, No. 225 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chromium(II) oxide (CrO) is an
crystallises in the rock salt structure.[2]
Hypophosphites may reduce chromium(III) oxide
to chromium(II) oxide:
- H3PO2 + 2 Cr2O3 → 4 CrO + H3PO4
It is readily oxidized by the atmosphere. CrO is basic, while CrO3 is acidic, and Cr2O3 is amphoteric.[3]
CrO occurs in the spectra of luminous red novae, which occur when two stars collide. It is not known why red novae are the only objects that feature this molecule; one possible explanation is an as-yet-unknown nucleosynthesis process.[4]
See also
- Chromium(IV) oxide
- Chromium(VI) oxide
References
- ISBN 978-81-7041-236-6
- ISBN 0-12-352651-5
- ^ Chemistry 7th edition, by Raymond Chang page 645 (problem 15.100)
- S2CID 118566357.