Color of water

Source: Wikipedia, the free encyclopedia.

a glass of transparent water sitting on a wooden table
When water is in small quantities (e.g. in a glass) it appears colorless to the human eye.

The color of water varies with the ambient conditions in which that water is present. While relatively small quantities of

elements
or suspended impurities may give water a different color.

Intrinsic color

An indoor swimming pool appears cyan from above, as light reflecting from the bottom of the pool travels through enough water that its red component is absorbed. The same water in a smaller bucket looks only slightly cyan,[1] and observing the water at close range makes it appear colorless to the naked eye.

The intrinsic color of liquid water may be demonstrated by looking at a white light source through a long pipe that is filled with purified water and closed at both ends with a transparent window. The light cyan color is caused by weak absorption in the red part of the visible spectrum.[2]

Absorptions in the visible spectrum are usually attributed to excitations of

vibration. Two stretching vibrations of the O–H bonds in the gaseous state of water occur at v1 = 3650 cm−1 and v3 = 3755 cm−1. Absorption due to these vibrations occurs in the infrared region of the spectrum. The absorption in the visible spectrum is due mainly to the harmonic v1 + 3v3 = 14,318 cm−1, which is equivalent to a wavelength of 698 nm. In liquid state at 20°C these vibrations are red-shifted by hydrogen bonding, resulting in red absorption at 740 nm, other harmonics such as v1 + v2 + 3v3 giving red absorption at 660 nm.[3] The absorption curve for heavy water (D2O) is of a similar shape, but is shifted further towards the infrared end of the spectrum, because the vibrational transitions have a lower energy. For this reason, heavy water does not absorb red light and thus large bodies of D2O would lack the characteristic cyan color of the more commonly found light water (1H2O).[4]

Absorption intensity decreases markedly with each successive overtone, resulting in very weak absorption for the third overtone. For this reason, the pipe needs to have a length of a meter or more and the water must be purified by microfiltration to remove any particles that could produce Mie scattering.

Color of lakes and oceans

Large bodies of water such as oceans manifest water's inherent blue color.
MODIS instruments of the Gulf of Mexico
.

Lakes and oceans appear cyan for several reasons. One is that the surface of the water reflects the color of the sky, which ranges from cyan to light azure. It is a common misconception that this reflection is the sole reason bodies of water appear cyan, though it can contribute. This contribution usually makes the body of water appear more a shade of azure rather than cyan depending on how bright the sky is. [5][6] Water in swimming pools with white-painted sides and bottom will appear cyan, even in indoor pools where there is no sky to be reflected. The deeper the pool, the more intense the cyan color becomes.[7]

Some of the light hitting the surface of ocean is reflected but most of it penetrates the water surface, interacting with water molecules and other substances in the water. Water molecules can vibrate in three different modes when they interact with light. The red, orange, and yellow wavelengths of light are absorbed so the remaining light seen is composed of green, cyan, and blue wavelengths. This is the main reason the ocean's color is cyan. The relative contribution of reflected skylight and the light scattered back from the depths is strongly dependent on observation angle.[8]

scattered
back up to the surface by small suspended particles.

Scattering from suspended particles also plays an important role in the color of lakes and oceans, causing the water to look greener or bluer in different areas. A few tens of meters of water will absorb all light, so without scattering, all bodies of water would appear black. Because most lakes and oceans contain suspended living matter and mineral particles, light from above is scattered and some of it is reflected upwards. Scattering from suspended particles would normally give a white color, as with snow, but because the light first passes through many meters of cyan-colored liquid, the scattered light appears cyan. In extremely pure water—as is found in mountain lakes, where scattering from particles is very low—the scattering from water molecules themselves also contributes a cyan color.[9][10]

Diffuse sky radiation due to Rayleigh scattering in the atmosphere along one's line of sight gives distant objects a cyan or light azure tint. This is most commonly noticed with distant mountains, but also contributes to the cyanness of the ocean in the distance.[citation needed]

Color of glaciers

Glaciers are large bodies of ice and snow formed in cold climates by processes involving the compaction of fallen snow. While snowy glaciers appear white from a distance, the long path lengths of internal reflected light causes glaciers to appear a deep blue when viewed up close and when shielded from direct ambient light.[citation needed]

Relatively small amounts of regular ice appear white because plenty of air bubbles are present, and also because small quantities of water appear to be colorless. In glaciers, on the other hand, the pressure causes the air bubbles, trapped in the accumulated snow, to be squeezed out increasing the density of the created ice. Large quantities of water appear cyan, therefore a large piece of compressed ice, or a glacier, would also appear cyan.

Color of water samples

lime give the water of Havasu Falls
a cyan color.

Dissolved and particulate material in water can cause it to be appear more green, tan, brown, or red. For instance, dissolved

tannins can result in dark brown colors, or algae floating in the water (particles) can impart a green color.[11] Color variations can be measured with reference to a standard color scale. Two examples of standard color scales for natural water bodies are the Forel-Ule scale and the Platinum-Cobalt scale. For example, slight discoloration is measured against the Platinum-Cobalt scale in Hazen units (HU).[12]

The color of a water sample can be reported as:

Testing for color can be a quick and easy test which often reflects the amount of organic material in the water, although certain inorganic components like iron or manganese can also impart color.

Water color can reveal physical, chemical and bacteriological conditions. In drinking water, green can indicate copper leaching from copper plumbing and can also represent algae growth. Blue can also indicate copper, or might be caused by syphoning of industrial cleaners in the tank of commodes, commonly known as backflowing. Reds can be signs of rust from iron pipes or airborne bacteria from lakes, etc. Black water can indicate growth of sulfur-reducing bacteria inside a hot water tank set to too low a temperature. This usually has a strong sulfur or rotten egg (H2S) odor and is easily corrected by draining the water heater and increasing the temperature to 49 °C (120 °F) or higher. The odor will always be in the hot water pipes if sulfate reducing bacteria are the cause and never in the cold water plumbing.[citation needed] Learning the water impurity indication color spectrum can make identifying and solving cosmetic, bacteriological and chemical problems easier.

Water quality and color

Glacial rock flour makes New Zealand's Lake Pukaki a lighter turquoise than its neighbors.

The presence of color in water does not necessarily indicate that the water is not

tannins are only toxic to animals in large concentration.[14]

Color from dissolved substances is not removed by typical

] Other factors can affect the color seen:

Color names

Red tide
off the California coast

Various cultures divide the semantic field of colors differently from the English language usage and some do not distinguish between blue and green in the same way. An example is Welsh where glas can mean blue or green, or Vietnamese where xanh likewise can mean either. Conversely, in Russian and some other languages, there is no single word for blue, but rather different words for light blue (голубой, goluboy) and dark blue (синий, siniy).

Other color names assigned to bodies of water are

red tide and black tide
.

The Ancient Greek poet

]

The Ancient Indian Wisdom of

Veda consider life giving contributions of water a part of divine and recognize water as a primeval God Varuna; and the color of Varuna is described as blue. In the Gayatri
associated with Varuna, the word "neela purusha" comes in second line which calls the water deity, the blue one.

References

  1. on 23 January 2012, retrieved 5 October 2011
  2. .
  3. ^ WebExhibits. "Colours from Vibration". Causes of Colour. WebExhibits. Archived from the original on 23 February 2017. Retrieved 21 October 2017. Heavy water is colourless because all of its corresponding vibrational transitions are shifted to lower energy (higher wavelength) by the increase in isotope mass.
  4. ^ Braun & Smirnov 1993, p. 612: "... any simple answer is bound to mislead. It turns out that contributions to the observed color are made both by reflected skylight and by the intrinsic absorption."
  5. ^ "Common Misconceptions About Oceans — Polar Oceans — Beyond Penguins and Polar Bears". 18 July 2011. Retrieved 5 July 2022.
  6. .
  7. ^ Braun & Smirnov 1993, p. 613: "... the relative contribution of reflected skylight and the light scattered back from the depths is strongly dependent on observation angle."
  8. S2CID 11061625
    .
  9. .
  10. .
  11. ^ International Organization for Standardization, ISO 2211:1973, Measurement of colour in Hazen units (platinum-cobalt scale) of Liquid Chemical Products
  12. ^ Wetzel, R. G. (2001). Limnology (3rd ed.). New York: Academic Press.
  13. ^ Cannas, Antonello. "Tannins: fascinating but sometimes dangerous molecules". Cornell University Department of Animal Science. Cornell University. Retrieved 25 September 2020.

Further reading

External links