Cyclosarin
This article includes a list of general references, but it lacks sufficient corresponding inline citations. (September 2017) |
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Names | |||
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Preferred IUPAC name
Cyclohexyl methylphosphonofluoridate | |||
Other names
GF;(Fluoro-methyl-phosphoryl)oxycyclohexane
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Identifiers | |||
3D model (
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ChemSpider | |||
PubChem CID
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UNII | |||
UN number | 2810 | ||
CompTox Dashboard (EPA)
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Properties | |||
C7H14FO2P | |||
Molar mass | 180.159 g·mol−1 | ||
Appearance | Colorless liquid | ||
Density | 1.1278 g/cm3 | ||
Melting point | −30 °C (−22 °F; 243 K) | ||
Boiling point | 239 °C (462 °F; 512 K) | ||
Almost insoluble | |||
Hazards | |||
Flash point | 94 °C (201 °F; 367 K) | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cyclosarin or GF (cyclohexyl methylphosphonofluoridate) is an extremely
As a
Chemical characteristics
Like its predecessor sarin, cyclosarin is a liquid organophosphate nerve agent. Its physical characteristics are, however, quite different from those of sarin.
At room temperature, cyclosarin is a colorless liquid whose odor has been variously described as sweet and musty,[2] or resembling peaches or shellac. Unlike sarin, cyclosarin is a persistent liquid, meaning that it has a low vapor pressure and therefore evaporates relatively slowly, at only about 1/69th the rate of sarin and 1/20th that of water.
Also unlike sarin, cyclosarin is
History
First synthesized during World War II as part of Nazi Germany's chemical weapons research on organophosphate compounds after their military potential was recognized, cyclosarin was also studied later in the United States and Great Britain in the early 1950s as part of a systematic study of potential nerve agents. It was never selected for mass production, however, due to its precursors being more expensive than those of other G-series nerve agents such as sarin (GB).
To date, Iraq is the only nation known to have manufactured significant quantities of cyclosarin for use as a chemical agent and to deploy it in battle. During the Iran–Iraq War (1980–1988), the Iraqis used sarin and cyclosarin together as a mixture. This was likely done to obtain a more persistent chemical agent as well as in response to an existing embargo placed on alcohol precursors for sarin.[3]
Munitions
Binary weapons
This section needs additional citations for verification. (July 2022) |
Like other nerve agents, cyclosarin can be shipped in
A cyclosarin binary weapon would most likely contain methylphosphonyl difluoride in one capsule, with the other capsule containing a mixture of cyclohexylamine and cyclohexanol.
GB-GF mixtures
Iraq fielded munitions filled with a mixture of GB (sarin) and GF (cyclosarin). Tests on mice indicated that GB-GF mixtures have a relative toxicity between GF and GB.[4]
References
- ISBN 978-0-849-31434-6
- ISBN 978-0-6151-3645-5
- ^ "Nerve Agent:GF". Archived from the original on January 8, 2009. Retrieved January 5, 2009.
- ^ "CBWInfo.com". Archived from the original on January 8, 2009. Retrieved March 1, 2012.
- United States Central Intelligence Agency. (July 15, 1996). Stability of Iraq's Chemical Weapon Stockpile Archived April 28, 2011, at the Wayback Machine Retrieved October 30, 2004
- Office of the Special Assistant for Gulf War Illnesses. (Oct. 19, 2004). Chemical Properties of Sarin and Cyclosarin Archived October 14, 2017, at the Wayback Machine Retrieved October 30, 2004
- Press release from Centcom confirming that the chemical munitions found by the Poles dated back to before the 1991 Gulf War, and, thus, could not represent a threat.