Diborane(4)

Source: Wikipedia, the free encyclopedia.
Diborane(4)
Names
IUPAC name
Diborane(4)
Identifiers
3D model (
JSmol
)
ChEBI
24760
  • InChI=1S/B2H4/c3-1-2(3)4-1/h1-2H ☒N
    Key: NTSBJDTWOAARNU-UHFFFAOYSA-N ☒N
  • [H]1[BH]2[H][BH]12
Properties
B2H4
Molar mass 25.65 g·mol−1
Related compounds
Related compounds
Tetrahydroxydiborane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Diborane(4) is a transient inorganic compound with the chemical formula B
2
H
4
. Stable derivatives are known.

Diborane(4) has been produced by abstraction of two hydrogen atoms from diborane(6) using atomic fluorine and detected by photoionization mass spectrometry.[1] Computational studies predict a structure in which are two hydrogen atoms bridging the two boron atoms via three-centre two-electron bonds in addition to the 2-centre, 2-electron bond between the two boron atoms and one terminal hydrogen atom bonded to each boron atom.[2]

Several stable derivatives of diborane(4) have been reported.[3][4][5]

References