Disulfur

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Disulfur
Ball and stick model of disulfur molecule
Names
IUPAC name
Disulfur[1]
Systematic IUPAC name
Disulfene
Other names
Diatomic sulfur

Sulfur dimer

Disulphur
Identifiers
3D model (
JSmol
)
ChEBI
ChemSpider
753
  • InChI=1S/S2/c1-2 checkY
    Key: MAHNFPMIPQKPPI-UHFFFAOYSA-N checkY
  • S=S
Properties
S2
Molar mass 64.12 g·mol−1
0 D
Thermochemistry
32.51 kJ K−1 mol−1
228.17 J K−1 mol−1
Std enthalpy of
formation
(ΔfH⦵298)
 128.60 kJ mol−1
Related compounds
Related compounds
 Triplet oxygen
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Disulfur is the

dioxygen molecule but rarely occurs at room temperature. This violet gas is the dominant species in hot sulfur vapors. S2 is one of the minor components of the atmosphere of Io, which is predominantly composed of SO2.[3] The instability of S2 is usually described in the context of the double bond rule
.

Synthesis

This violet gas is generated by heating sulfur above 720 °C, comprising 99% of the vapor at low pressure (1 mm Hg) at 530 °C.

Disulfur can be produced when an atmosphere of COS is irradiated with UV light using a mercury photosensitizer or when CS2, H2S2, S2Cl2 or C2H4S, PSF3 or COS are irradiated.[4]

Natural occurrence

Gaseous disulfur has been detected emanating from the surface of Jupiter's moon Io, from the vicinity of Pele volcano.[5]

Properties

The ground state of S2 is a triplet: a diradical, with two unpaired electrons like O2 and SO. It has the S-S bond length of 189 pm, much shorter than the S-S single bonds in S8, which are 206 pm long. Its Raman spectrum consists of a band at 715 cm−1.[6] The corresponding O-O band for O2 is found at 1556 cm−1.[7] The S-S bond energy is 430 kJ/mol compared to 498 kJ/mol for O2.[8]

Disulfur readily photodissociates,[9] with a mean lifespan of 7.5 min in sunlight.[10]

References

  1. ^ ebi.ac.uk/chebi/searchId.do?chebiId=29387
  2. ISBN 978-3-540-40191-9
    .
  3. S2CID 121867974
    .
  4. doi:10.1016/S0040-4020(97)00555-3
    .
  5. PMID 10817990
    .
  6. ISBN 978-3-540-40378-4
    .
  7. doi:10.1016/0022-2852(83)90029-2
    .
  8. ISBN 0-8493-0487-3
    .
  9. PMID 19754091
    .
  10. ISSN 0004-637X
    .

External links

  • Media related to Disulfur at Wikimedia Commons
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