Macroscopic quantum phenomena
Macroscopic quantum phenomena are processes showing quantum behavior at the macroscopic scale, rather than at the atomic scale where quantum effects are prevalent. The best-known examples of macroscopic quantum phenomena are superfluidity and superconductivity; other examples include the quantum Hall effect, Josephson effect and topological order. Since 2000 there has been extensive experimental work on quantum gases, particularly Bose–Einstein condensates.
Between 1996 and 2016 six
Quantum phenomena are generally classified as macroscopic when the quantum states are occupied by a large number of particles (of the order of the
Consequences of the macroscopic occupation
The concept of macroscopically occupied quantum states is introduced by Fritz London.[4][5] In this section it will be explained what it means if a single state is occupied by a very large number of particles. We start with the wave function of the state written as
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(1)
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with Ψ0 the amplitude and the phase. The wave function is normalized so that
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(2)
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The physical interpretation of the quantity
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(3)
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depends on the number of particles. Fig. 1 represents a container with a certain number of particles with a small control volume ΔV inside. We check from time to time how many particles are in the control box. We distinguish three cases:
- There is only one particle. In this case the control volume is empty most of the time. However, there is a certain chance to find the particle in it given by Eq. (3). The probability is proportional to ΔV. The factor ΨΨ∗ is called the chance density.
- If the number of particles is a bit larger there are usually some particles inside the box. We can define an average, but the actual number of particles in the box has relatively large fluctuations around this average.
- In the case of a very large number of particles there will always be a lot of particles in the small box. The number will fluctuate but the fluctuations around the average are relatively small. The average number is proportional to ΔV and ΨΨ∗ is now interpreted as the particle density.
In quantum mechanics the particle probability flow density Jp (unit: particles per second per m2), also called probability current, can be derived from the Schrödinger equation to be
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(4)
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with q the charge of the particle and the vector potential; cc stands for the complex conjugate of the other term inside the brackets.[6] For neutral particles q = 0, for superconductors q = −2e (with e the elementary charge) the charge of Cooper pairs. With Eq. (1)
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(5)
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If the wave function is macroscopically occupied the particle probability flow density becomes a particle flow density. We introduce the fluid velocity vs via the mass flow density
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(6)
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The density (mass per volume) is
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(7)
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so Eq. (5) results in
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(8)
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This important relation connects the velocity, a classical concept, of the condensate with the phase of the wave function, a quantum-mechanical concept.
Superfluidity
At temperatures below the lambda point, helium shows the unique property of superfluidity. The fraction of the liquid that forms the superfluid component is a macroscopic quantum fluid. The helium atom is a neutral particle, so q = 0. Furthermore, when considering helium-4, the relevant particle mass is m = m4, so Eq. (8) reduces to
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(9)
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For an arbitrary loop in the liquid, this gives
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(10)
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Due to the single-valued nature of the wave function
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(11a)
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with n integer, we have
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(11b)
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The quantity
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(12)
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is the quantum of circulation. For a circular motion with radius r
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(13)
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In case of a single quantum (n = 1)
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(14)
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When superfluid helium is put in rotation, Eq. (13) will not be satisfied for all loops inside the liquid unless the rotation is organized around vortex lines (as depicted in Fig. 2). These lines have a vacuum core with a diameter of about 1 Å (which is smaller than the average particle distance). The superfluid helium rotates around the core with very high speeds. Just outside the core (r = 1 Å), the velocity is as large as 160 m/s. The cores of the vortex lines and the container rotate as a solid body around the rotation axes with the same angular velocity. The number of vortex lines increases with the angular velocity (as shown in the upper half of the figure). Note that the two right figures both contain six vortex lines, but the lines are organized in different stable patterns.[7]
Superconductivity
In the original paper[8] Ginzburg and Landau observed the existence of two types of superconductors depending on the energy of the interface between the normal and superconducting states. The
The most important finding from
Fluxoid quantization
For
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(15)
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Integrating Eq. (15) over a closed loop gives
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(16)
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As in the case of helium we define the vortex strength
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(17)
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and use the general relation
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(18)
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where Φ is the magnetic flux enclosed by the loop. The so-called
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(19)
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In general the values of κ and Φ depend on the choice of the loop. Due to the single-valued nature of the wave function and Eq. (16) the fluxoid is quantized
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(20)
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The unit of quantization is called the
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(21)
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The flux quantum plays a very important role in superconductivity. The earth magnetic field is very small (about 50 μT), but it generates one flux quantum in an area of 6 μm by 6 μm. So, the flux quantum is very small. Yet it was measured to an accuracy of 9 digits as shown in Eq. (21). Nowadays the value given by Eq. (21) is exact by definition.
In Fig. 3 two situations are depicted of superconducting rings in an external magnetic field. One case is a thick-walled ring and in the other case the ring is also thick-walled, but is interrupted by a weak link. In the latter case we will meet the famous
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(22)
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Thick ring
The first case is a thick ring in an external magnetic field (Fig. 3a). The currents in a superconductor only flow in a thin layer at the surface. The thickness of this layer is determined by the so-called London penetration depth. It is of μm size or less. We consider a loop far away from the surface so that vs = 0 everywhere so κ = 0. In that case the fluxoid is equal to the magnetic flux (Φv = Φ). If vs = 0 Eq. (15) reduces to
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(23)
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Taking the rotation gives
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(24)
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Using the well-known relations and shows that the magnetic field in the bulk of the superconductor is zero as well. So, for thick rings, the total magnetic flux in the loop is quantized according to
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(25)
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Interrupted ring, weak links
Weak links play a very important role in modern superconductivity. In most cases weak links are oxide barriers between two superconducting thin films, but it can also be a crystal boundary (in the case of
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(26)
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The line integral is over the contact from one side to the other in such a way that the end points of the line are well inside the bulk of the superconductor where vs = 0. So the value of the line integral is well-defined (e.g. independent of the choice of the end points). With Eqs. (19), (22), and (26)
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(27)
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Without proof we state that the supercurrent through the weak link is given by the so-called DC
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(28)
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The voltage over the contact is given by the AC Josephson relation
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(29)
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The names of these relations (DC and AC relations) are misleading since they both hold in DC and AC situations. In the steady state (constant ) Eq. (29) shows that V=0 while a nonzero current flows through the junction. In the case of a constant applied voltage (voltage bias) Eq. (29) can be integrated easily and gives
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(30)
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Substitution in Eq. (28) gives
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(31)
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This is an AC current. The frequency
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(32)
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is called the Josephson frequency. One μV gives a frequency of about 500 MHz. By using Eq. (32) the flux quantum is determined with the high precision as given in Eq. (21).
The energy difference of a Cooper pair, moving from one side of the contact to the other, is ΔE = 2eV. With this expression Eq. (32) can be written as ΔE = hν which is the relation for the energy of a photon with frequency ν.
- The AC Josephson relation (Eq. (London equation's[14]). We start with Newton's law
- Substituting the expression for the Lorentz force and using the general expression for the co-moving time derivativegives
- Eq. (8) gives so
- Take the line integral of this expression. In the end points the velocities are zero so the ∇v2 term gives no contribution. Using and Eq. (26), with q = −2e and m = 2me, gives Eq. (29).
DC SQUID
Fig. 5 shows a so-called DC SQUID. It consists of two superconductors connected by two weak links. The fluxoid quantization of a loop through the two bulk superconductors and the two weak links demands
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(33)
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If the self-inductance of the loop can be neglected the magnetic flux in the loop Φ is equal to the applied flux
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(34)
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with B the magnetic field, applied perpendicular to the surface, and A the surface area of the loop. The total supercurrent is given by
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(35)
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Substitution of Eq(33) in (35) gives
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(36)
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Using a well known geometrical formula we get
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(37)
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Since the sin-function can vary only between −1 and +1 a steady solution is only possible if the applied current is below a critical current given by
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(38)
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Note that the critical current is periodic in the applied flux with period Φ0. The dependence of the critical current on the applied flux is depicted in Fig. 6. It has a strong resemblance with the interference pattern generated by a laser beam behind a double slit. In practice the critical current is not zero at half integer values of the flux quantum of the applied flux. This is due to the fact that the self-inductance of the loop cannot be neglected.[15]
Type II superconductivity
Type-II superconductivity is characterized by two critical fields called Bc1 and Bc2. At a magnetic field Bc1 the applied magnetic field starts to penetrate the sample, but the sample is still superconducting. Only at a field of Bc2 the sample is completely normal. For fields in between Bc1 and Bc2 magnetic flux penetrates the superconductor in well-organized patterns, the so-called Abrikosov vortex lattice similar to the pattern shown in Fig. 2.[16] A cross section of the superconducting plate is given in Fig. 7. Far away from the plate the field is homogeneous, but in the material superconducting currents flow which squeeze the field in bundles of exactly one flux quantum. The typical field in the core is as big as 1 tesla. The currents around the vortex core flow in a layer of about 50 nm with current densities on the order of 15×1012 A/m2. That corresponds with 15 million ampère in a wire of one mm2.
Dilute quantum gases
The classical types of quantum systems, superconductors and superfluid helium, were discovered in the beginning of the 20th century. Near the end of the 20th century, scientists discovered how to create very dilute atomic or molecular gases, cooled first by laser cooling and then by evaporative cooling.[17] They are trapped using magnetic fields or optical dipole potentials in ultrahigh vacuum chambers. Isotopes which have been used include rubidium (Rb-87 and Rb-85), strontium (Sr-87, Sr-86, and Sr-84) potassium (K-39 and K-40), sodium (Na-23), lithium (Li-7 and Li-6), and hydrogen (H-1). The temperatures to which they can be cooled are as low as a few nanokelvin. The developments have been very fast in the past few years. A team of NIST and the University of Colorado has succeeded in creating and observing vortex quantization in these systems.[18] The concentration of vortices increases with the angular velocity of the rotation, similar to the case of superfluid helium and superconductivity.
See also
- Charge density wave
- Chiral magnetic effect
- Domain wall (magnetism)
- Flux pinning
- Flux quantization
- Ginzburg–Landau theory
- Husimi Q representation
- Josephson effect
- Magnetic flux quantum
- Meissner effect
- N-slit interferometric equation
- Quantum boomerang effect
- Quantum turbulence
- Quantum vortex
- Schrödinger's cat paradox
- Second sound
- SQUID
- Superconductivity
- Topological defect
- Type-I superconductor
- Type-II superconductor
References and footnotes
- topological phases of matter(2016).
- ^ D.R. Tilley and J. Tilley, Superfluidity and Superconductivity, Adam Hilger, Bristol and New York, 1990
- .
- ^ Fritz London Superfluids (London, Wiley, 1954–1964)
- .
- ^ "The Feynman Lectures on Physics Vol. III Ch. 21: The Schrödinger Equation in a Classical Context: A Seminar on Superconductivity, Section 21-5: Superconductivity". feynmanlectures.caltech.edu. Retrieved 2020-01-12.
- S2CID 120018419.
- ^ Landau, Lev Davidovich; Ginzburg, Vitaly L (1950). "On the theory of superconductivity". Zh. Eksp. Teor. Fiz. 20.
- ^
Lev D. Landau; Evgeny M. Lifschitz (1984). Electrodynamics of Continuous Media. ISBN 978-0-7506-2634-7.
- ^ David J. E. Callaway (1990). "On the remarkable structure of the superconducting intermediate state". .
- PMID 15298378.
- ^ M. Tinkham (1975). Introduction to Superconductivity. McGraw-Hill.
- .
- .
- .
- .
- PMID 17789847.
- PMID 15323808.