Mellitic anhydride

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Mellitic anhydride
Mellitic anhydride molecule
Names
Preferred IUPAC name
Benzo[1,2-c:3,4-c′:5,6-c′′]trifuran-1,3,4,6,7,9-hexone
Identifiers
3D model (
JSmol
)
ChemSpider
UNII
  • InChI=1S/C12O9/c13-7-1-2(8(14)19-7)4-6(12(18)21-11(4)17)5-3(1)9(15)20-10(5)16 ☒N
    Key: NNYHMCFMPHPHOQ-UHFFFAOYSA-N ☒N
  • InChI=1/C12O9/c13-7-1-2(8(14)19-7)4-6(12(18)21-11(4)17)5-3(1)9(15)20-10(5)16
    Key: NNYHMCFMPHPHOQ-UHFFFAOYAV
  • O=C2OC(=O)c1c4c(c3c(c12)C(=O)OC3=O)C(=O)OC4=O
Properties
C12O9
Molar mass 288.123 g·mol−1
Appearance colorless solid[1]
Melting point 161 °C; 322 °F; 434 K[1]
Vapor pressure 0.000004 mmHg (20°C)[1]
Hazards
NIOSH (US health exposure limits):
PEL (Permissible)
none[1]
REL (Recommended)
TWA 0.005 ppm (0.04 mg/m3) Should be handled in the workplace as an extremely toxic substance.[1]
IDLH
(Immediate danger)
N.D.[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Mellitic anhydride, the anhydride of mellitic acid, is an organic compound with the formula C12O9.

Containing no other elements (e.g., hydrogen) besides carbon and oxygen, mellitic anhydride is an

Justus Liebig and Friedrich Wöhler in 1830 in their study of mellite ("honey stone") and has the empirical formula C4O3.[2][3][4] The substance was properly characterized in 1913 by H. Meyer and K. Steiner.[5][6] It retains the aromatic character of the benzene ring.[7][8]

References

  1. ^ a b c d e f NIOSH Pocket Guide to Chemical Hazards. "#0635". National Institute for Occupational Safety and Health (NIOSH).
  2. .
  3. .
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  5. .
  6. ^ Bugge, G. (1914). "Chemie: Ein neues Kohlenoxyd". Naturwissenschaftliche Wochenschrift. 13/29 (12): 188.
  7. PMID 17315989
    .
  8. .