Meteoric iron

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Meteoric iron (native iron)
Widmanstätten pattern on a 500g endcut from the Toluca iron meteorite
General
CategoryNative element mineral
Formula
(repeating unit)
Fe and Ni in different ratios
Space groupDifferent structures
Identification
LusterMetallic
DiaphaneityOpaque

Meteoric iron, sometimes meteoritic iron,

meteorites and made from the elements iron and nickel, mainly in the form of the mineral phases kamacite and taenite. Meteoric iron makes up the bulk of iron meteorites but is also found in other meteorites. Apart from minor amounts of telluric iron, meteoric iron is the only naturally occurring native metal of the element iron (in metallic form rather than in an ore) on the Earth's surface.[2]

Mineralogy

The bulk of meteoric iron consists of taenite and kamacite. Taenite is a face-centered cubic and kamacite a body-centered cubic iron-nickel alloy.

Meteoric iron can be distinguished from telluric iron by its microstructure and perhaps by its chemical composition also, since meteoritic iron contains more nickel and less carbon.[2]

Trace amounts of

stony iron meteorites is identical to the "gallium-germanium group" of the iron meteorites.[3]

Overview over meteoric iron mineral phases
Mineral Formula Nickel (Mass-% Ni) Crystal structure Notes & references
Antitaenite γLow Spin-(Ni,Fe) 20–40 face centered cubic Only approved as a variety of taenite by the IMA
Kamacite α-(Fe,Ni); Fe0+0.9Ni0.1 5–10 body centered cubic Same structure as ferrite
Taenite γ-(Ni,Fe) 20–65 face centered cubic Same structure as austenite
Tetrataenite (FeNi) 48–57 tetragonal [4]

Structures

Meteoric iron forms a few different structures that can be seen by

exsolved from taenite in the form of lamellas.[5] Plessite is a more fine-grained intergrowth of the two minerals in between the lamella of the Widmanstätten pattern.[6] Neumann lines are fine lines running through kamacite crystals that form through impact-related deformation.[7]

Cultural and historical usage

A lance made from a narwhal tusk with an iron head made from the Cape York meteorite.

Before the advent of iron smelting, meteoric iron was the only source of iron metal apart from minor amounts of telluric iron. Meteoric iron was already used before the beginning of the Iron Age to make cultural objects, tools and weapons.[8]

Bronze Age

Iron in hieroglyphs
biAF18
n
pt

bjꜣ-n-p.t
literally "metal of the sky"

Many examples of iron working from the Bronze Age have been confirmed to be meteoritic in origin.[9]

The Americas

Africa

  • Fragments from the Gibeon meteorite were used for centuries by the Nama people of Namibia.

Asia

  • There are reports of the use of meteorites for manufacture of various items in Tibet (see Thokcha).
  • The Iron Man, a purported Tibetan Buddhist statue of Vaiśravaṇa, was likely carved from an ataxite meteorite.[19] It has been speculated that it may be made from a fragment of the Chinga meteorite.[20][21]

Even after the invention of smelting, meteoric iron was sometimes used where this technology was not available or metal was scarce. A piece of the Cranbourne meteorite was made into a horseshoe around 1854.[22]

Today meteoritic iron is used in niche jewellery and knife production, but most of it is used for research, educational or collecting purposes.

Atmospheric phenomena

Meteoric iron also has an effect on the Earth's atmosphere. When meteorites descend through the atmosphere, outer parts are ablated. Meteoric ablation is the source of many elements in the upper atmosphere. When meteoric iron is ablated, it forms a free iron atom that can react with ozone (O3) to form FeO. This FeO may be the source of the orange spectrographic bands in the spectrum of the upper atmosphere.[23]

See also

References

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  2. ^ .
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  8. ^ .
  9. ^ "Pre-Dynastic Iron Beads from Gerzeh, Egypt". ucl.ac.uk. Archived from the original on 7 April 2015. Retrieved 28 December 2012.
  10. .
  11. .
  12. .
  13. ^ Walsh, Declan (2 June 2016). "King Tut's Dagger Made of 'Iron From the Sky,' Researchers Say". The New York Times. Retrieved 4 June 2016. ...the blade's composition of iron, nickel and cobalt was an approximate match for a meteorite that landed in northern Egypt. The result "strongly suggests an extraterrestrial origin"
  14. ^ Guy, Jack (8 August 2023). "Arrowhead made from meteorite 3,000 years ago found near lake in Europe". CNN. Retrieved 9 August 2023.
  15. ^ Iron and steel in ancient times by Vagn Fabritius Buchwald - Det Kongelige Danske Videnskabernes Selskab 2005
  16. JSTOR 2844401
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  17. .
  18. ^ Der Lama mit der Hose: „Buddha from space“ ist offenbar eine Fälschung (Telepolis 13.10.2012)
  19. ^ "Ancient Buddhist Statue Made of Meteorite, New Study Reveals". Science Daily. Retrieved 26 December 2012.
  20. .
  21. ^ "The Cranbourne Meteorites" (PDF). City of Casey. Archived from the original (PDF) on 10 May 2013. Retrieved 29 December 2012.
  22. S2CID 130887275
    .

External links