Miyaura borylation

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Miyaura borylation
Named after Norio Miyaura
Reaction type Organic redox reaction
Identifiers
Organic Chemistry Portal miyaura-borylation-reaction

Miyaura borylation, also known as the Miyaura borylation reaction, is a

boronates from vinyl or aryl halides with the cross-coupling of bis(pinacolato)diboron in basic conditions with a catalyst such as PdCl2(dppf). The resulting borylated products can be used as coupling partners for the Suzuki reaction.[1]

Scope

The Miyaura borylation has shown to work for:

Alkyl halides,

carbonyl compounds,[10] and vinyl triflates.[11]

See also

References

  1. ^
    doi:10.1021/jo00128a024
    .
  2. PMID 22668072
    .
  3. doi:10.1055/s-0036-1591549
    .
  4. PMID 21319836
    .
  5. PMID 21105666
    .
  6. PMID 22994557
    .
  7. doi:10.1055/s-2005-861791
    .
  8. PMID 23777538
    .
  9. hdl:2115/56184
    .
  10. hdl:2115/14605
    .
  11. PMID 12095344
    .
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