Oleochemistry
Oleochemistry is the study of
As the price of crude oil rose in the late 1970s,[2] manufacturers switched from petrochemicals to oleochemicals[3] because plant-based lauric oils processed from palm kernel oil were cheaper. Since then, palm kernel oil is predominantly used in the production of laundry detergent and personal care items like toothpaste, soap bars, shower cream and shampoo.[4]
Processes
Important process in oleochemical manufacturing include hydrolysis and transesterification, among others.[1]
Hydrolysis
The splitting (or hydrolysis) of the triglycerides produces fatty acids and glycerol follows this equation:
- RCO2CH2–CHO2CR–CH2O2CR + 3 H2O → 3 RCOOH + HOCH2–CHOH–CH2OH
To this end, hydrolysis is conducted in water at 250 °C. The cleavage of triglycerides with base proceeds more quickly than hydrolysis, the process being saponification. Saponification however produces soap, whereas the desired product of hydrolysis are the fatty acids.
Transesterification
Fats react with alcohols (R'OH) instead of with water in hydrolysis) in a process called transesterification. Glycerol is produced together with the fatty acid esters. Most typically, the reaction entails the use of methanol (MeOH) to give fatty acid methyl esters:
- RCO2CH2–CHO2CR–CH2O2CR + 3 MeOH → 3 RCO2Me + HOCH2–CHOH–CH2OH
FAMEs are less viscous than the precursor fats and can be purified to give the individual fatty acid esters, e.g. methyl oleate vs methyl palmitate.
Hydrogenation
The fatty acid or fatty esters are susceptible to
Gelation
Liquid oil can also be immobilized in a 3D-network provided by various molecules called oleogelators.[6]
Applications
The largest application for oleochemicals, about 30% of market share for fatty acids and 55% for fatty alcohols, is for making
Other applications of oleochemicals include the production of
Oleochemical industry development
Europe
Through the 1996 creation of Novance and the 2008 acquisition of Oleon, Avril Group has dominated the European market of oleochemistry.[8]
Southeast Asia
Southeast Asian countries' rapid production growth of palm oil and palm kernel oil in the 1980s spurred the oleochemical industry in Malaysia, Indonesia, and Thailand. Many oleochemical plants were built. Though a nascent and small industry when pitted against big detergent giants in the US and Europe, oleochemical companies in southeast Asia had competitive edge in cheap ingredients.[9] The US fatty chemical industry found it difficult to consistently maintain acceptable levels of profits. Competition was intense with market shares divided among many companies there where neither imports nor exports played a significant role.[10] By the late 1990s, giants like Henkel, Unilever, and Petrofina sold their oleochemical factories to focus on higher profit activities like retail of consumer goods. Since the Europe outbreak of 'mad cow disease' or (bovine spongiform encephalopathy) in 2000, tallow is replaced for many uses by vegetable oleic fatty acids, such as palm kernel and coconut oils.[7]: 24
References
- ^ S2CID 28601501.
- S2CID 95637088.
- S2CID 94948265.
- S2CID 97742057.
- ^ Maria Scharfe, Eckhard Flöter Oleogelation: From Scientific Feasibility to Applicability in Food Products https://doi.org/10.1002/ejlt.202000213
- ^ a b c The Changing World of Oleochemicals Wolfgang Rupilius and Salmiah Ahmad, Palm Oil Developments 44, 2005
- ^ "Activity Report 2014 A new springtime for the oils and proteins sectors". 2014. p. 41.
- ^ The Future of Palm Oil in Oleochemicals Appalasami & de Vries, Palm Oil Developments 14-3, 1990
- S2CID 95963786.