Polyester
Polyester is a category of
Polyester fibers are sometimes spun together with natural fibers to produce a
Liquid crystalline polyesters are among the first industrially used
Types
Polyesters are one of the most economically important classes of polymers, driven especially by PET, which is counted among the commodity plastics; in 2019 around 30.5 million metric tons were produced worldwide.[4] There is a great variety of structures and properties in the polyester family, based on the varying nature of the R group (see first figure with blue ester group).[1]
Natural
Polyesters occurring in nature include the cutin component of plant cuticles, which consists of omega hydroxy acids and their derivatives, interlinked via ester bonds, forming polyester polymers of indeterminate size. Polyesters are also produced by bees in the genus Colletes, which secrete a cellophane-like polyester lining for their underground brood cells[5] earning them the nickname "polyester bees".[6]
Synthetic
The family of synthetic polyesters comprises[1]
- Linear aliphatic high molecular weight polyesters (Mn >10,000) are low-melting (m. p. 40 – 80 °C) semicrystalline polymers and exhibit relatively poor mechanical properties. Their inherent degradability, resulting from their hydrolytic instability, makes them suitable for applications where a possible environmental impact is a concern, e.g. packaging, disposable items or agricultural mulch films[7] or in biomedical and pharmaceutical applications.[8]
- Aliphatic linear low-molar-mass (Mn < 10,000) hydroxy-terminated polyesters are used as macromonomers for the production of polyurethanes.
- hyperbranched polyesters are used as rheology modifiers in thermoplastics or as crosslinkers in coatings[9] due to their particularly low viscosity, good solubility and high functionality[10]
- Aliphatic–aromatic polyesters, including poly(ethylene terephthalate) (PET) and poly(butylene terephthalate) (PBT), poly(hexamethylene terephthalate)(PHT), poly(propylene terephthalate) (PTT, Sorona), etc. are high-melting semicrystalline materials (m. p. 160–280 °C) that and have benefited from engineering thermoplastics, fibers and films.
- Wholly aromatic linear copolyesters present superior mechanical properties and heat resistance and are used in a number of high-performance applications.
- sheet molding compounds, as fiberglass laminating resins and in non-metallic auto-body fillers. They are also used as the thermoset polymer matrix in pre-pregs. Fiberglass-reinforced unsaturated polyesters find wide application in bodies of yachts and as body parts of cars.
Depending on the chemical structure, polyester can be a
Increasing the aromatic parts of polyesters increases their
Polyesters can also be
Aliphatic vs. aromatic polymers
Thermally stable polymers, which generally have a high proportion of aromatic structures, are also called high-performance plastics. This application-oriented classification compares such polymers with engineering plastics and commodity plastics. The continuous service temperature of high-performance plastics is generally stated as being higher than 150 °C,[12] whereas engineering plastics (such as polyamide or polycarbonate) are often defined as thermoplastics that retain their properties above 100 °C.[13] Commodity plastics (such as polyethylene or polypropylene) have in this respect even greater limitations, but they are manufactured in great amounts at low cost.
Poly(ester
The generally poor processability of aromatic polymers (for example, a high melting point and a low solubility) also limits the available options for synthesis and may require strong electron-donating co-solvents like HFIP or TFA for analysis (e. g.
Uses and applications
Fabrics
Polyesters are also used to make bottles, films,
Production
Basics
This section needs to be updated.(January 2023) |
There are several reasons for the importance of polyethylene terephthalate:
- The relatively easy accessible raw materials PTA or DMT and MEG
- The very well understood and described simple chemical process of its synthesis
- The low toxicity level of all raw materials and side products during production and processing
- The possibility to produce PET in a closed loop at low emissions to the environment
- The outstanding mechanical and chemical properties
- The recyclability
- The wide variety of intermediate and final products.
In the following table, the estimated world polyester production is shown. Main applications are textile polyester, bottle polyester resin, film polyester mainly for packaging and specialty polyesters for engineering plastics.
Product type | 2002 (million tonnes/year) | 2008 (million tonnes/year) |
---|---|---|
Textile-PET | 20 | 39 |
Resin, bottle/A-PET | 9 | 16 |
Film-PET | 1.2 | 1.5 |
Special polyester | 1 | 2.5 |
Total | 31.2 | 59 |
Polyester processing
After the first stage of polymer production in the melt phase, the product stream divides into two different application areas which are mainly textile applications and packaging applications. In the following table, the main applications of textile and packaging of polyester are listed.
Textile | Packaging |
---|---|
Staple fiber (PSF) | Bottles for CSD, water, beer, juice, detergents, etc. |
Filaments POY, DTY, FDY | A-PET film |
Technical yarn and tire cord | Thermoforming |
Non-woven and spunbond | biaxial-oriented film (BO-PET) |
Mono-filament | Strapping |
Abbreviations:
- PSF
- Polyester-staple fiber
- POY
- Partially oriented yarn
- DTY
- Drawn textured yarn
- FDY
- Fully drawn yarn
- CSD
- Carbonated soft drink
- A-PET
- Amorphous polyethylene terephthalate film
- BO-PET
- Biaxial-oriented polyethylene terephthalate film
A comparable small market segment (much less than 1 million tonnes/year) of polyester is used to produce engineering plastics and masterbatch.
In order to produce the polyester melt with a high efficiency, high-output processing steps like staple fiber (50–300 tonnes/day per spinning line) or POY /FDY (up to 600 tonnes/day split into about 10 spinning machines) are meanwhile more and more vertically integrated direct processes. This means the polymer melt is directly converted into the textile fibers or filaments without the common step of pelletizing. We are talking about full vertical integration when polyester is produced at one site starting from crude oil or distillation products in the chain oil → benzene → PX → PTA → PET melt → fiber/filament or bottle-grade resin. Such integrated processes are meanwhile established in more or less interrupted processes at one production site. Eastman Chemicals were the first to introduce the idea of closing the chain from PX to PET resin with their so-called INTEGREX process. The capacity of such vertically integrated production sites is >1000 tonnes/day and can easily reach 2500 tonnes/day.
Besides the above-mentioned large processing units to produce staple fiber or yarns, there are ten thousands of small and very small processing plants, so that one can estimate that polyester is processed and recycled in more than 10 000 plants around the globe. This is without counting all the companies involved in the supply industry, beginning with engineering and processing machines and ending with special additives, stabilizers and colors. This is a gigantic industry complex and it is still growing by 4–8% per year, depending on the world region.
Synthesis
Synthesis of polyesters is generally achieved by a polycondensation reaction. The general equation for the reaction of a diol with a diacid is:
- (n+1) R(OH)2 + n R'(COOH)2 → HO[ROOCR'COO]nROH + 2n H2O.
Polyesters can be obtained by a wide range of reactions of which the most important are the reaction of acids and alcohols, alcoholysis and or acidolysis of low-molecular weight esters or the alcoholysis of acyl chlorides. The following figure gives an overview over such typical polycondensation reactions for polyester production. Furthermore, polyesters are accessible via ring-opening polymerization.
Azeotrope esterification is a classical method for condensation. The water formed by the reaction of
Direct bulk polyesterification at high temperatures (150 – 290 °C) is well-suited and used on the industrial scale for the production of aliphatic, unsaturated, and aromatic–aliphatic polyesters. Monomers containing
Alcoholic transesterification
Transesterification: An alcohol-terminated oligomer and an ester-terminated oligomer condense to form an ester linkage, with loss of an alcohol. R and R' are the two oligomer chains, R'' is a sacrificial unit such as a methyl group (methanol is the byproduct of the esterification reaction).
The term "transesterification" is typically used to describe hydroxy–ester, carboxy–ester, and ester–ester exchange reactions. The hydroxy–ester exchange reaction possesses the highest rate of reaction and is used for the production of numerous aromatic–aliphatic and wholly aromatic polyesters.[4] The transesterification based synthesis is particularly useful for when high melting and poorly soluble dicarboxylic acids are used. In addition, alcohols as condensation product are more volatile and thereby easier to remove than water.[17]
The high-temperature melt synthesis between bisphenol diacetates and aromatic dicarboxylic acids or in reverse between bisphenols and aromatic dicarboxylic acid diphenyl esters (carried out at 220 to 320 °C upon the release of acetic acid) is, besides the acyl chloride based synthesis, the preferred route to wholly aromatic polyesters.[4]
Acylation
In acylation, the acid begins as an acyl chloride, and thus the polycondensation proceeds with emission of hydrochloric acid (HCl) instead of water.
The reaction between diacyl chlorides and alcohols or phenolic compounds has been widely applied to polyester synthesis and has been subject of numerous reviews and book chapters.[4][18][19][20] The reaction is carried out at lower temperatures than the equilibrium methods; possible types are the high-temperature solution condensation, amine catalysed and interfacial reactions. In addition, the use of activating agents is counted as non-equilibrium method. The equilibrium constants for the acyl chloride-based condensation yielding yielding arylates and polyarylates are very high indeed and are reported to be 4.3 × 103 and 4.7 × 103, respectively. This reaction is thus often referred to as a 'non-equilibrium' polyesterification. Even though the acyl chloride based synthesis is also subject of reports in the patent literature, it is unlikely that the reaction is utilized on the production scale.[21] The method is limited by the acid dichlorides' high cost, its sensitivity to hydrolysis and the occurrence of side reactions.[22]
The high temperature reaction (100 to > 300 °C) of an diacyl chloride with an dialcohol yields the polyester and hydrogen chloride. Under these relatively high temperatures the reaction proceeds rapidly without a catalyst:[20]
The conversion of the reaction can be followed by titration of the evolved hydrogen chloride. A wide variety of solvents has been described including chlorinated benzenes (e.g. dichlorobenzene), chlorinated naphthalenes or diphenyls, as well as non-chlorinated aromatics like terphenyls, benzophenones or dibenzylbenzenes. The reaction was also applied successfully to the preparation of highly crystalline and poorly soluble polymers which require high temperatures to be kept in solution (at least until a sufficiently high molecular weight was achieved).[22]
In an interfacial acyl chloride-based reaction, the alcohol (generally in fact a phenol) is dissolved in the form of an alkoxide in an aqueous
The procedure is used for the production of
While acyl chloride-based polyesterifications proceed only very slowly at room temperature without a catalyst, the amine accelerates the reaction in several possible ways, although the mechanism is not fully understood.
- Silyl method
- In this variant of the HCl method, the carboxylic acid chloride is converted with the trimethyl silyl etherof the alcohol component and production of trimethyl silyl chloride is obtained
Acetate method (esterification)
- Silyl acetate method
Ring-opening polymerization
Other methods
Numerous other reactions have been reported for the synthesis of selected polyesters, but are limited to laboratory-scale syntheses using specific conditions, for example using dicarboxylic acid salts and dialkyl halides or reactions between bisketenes and diols.[4]
Instead of acyl chlorides, so-called activating agents can be used, such as
The use of activating agents for the production of high-melting aromatic polyesters and polyamides under mild conditions has been subject of intensive academic research since the 1980s, but the reactions have not gained commercial acceptance as similar results can be achieved with cheaper reactants.[4]
Thermodynamics of polycondensation reactions
Polyesterifications are grouped by some authors[4][18] into two main categories: a) equilibrium polyesterifications (mainly alcohol-acid reaction, alcohol–ester and acid–ester interchange reactions, carried out in bulk at high temperatures), and b) non-equilibrium polyesterifications, using highly reactive monomers (for example acid chlorides or activated carboxylic acids, mostly carried out at lower temperatures in solution).
The acid-alcohol based polyesterification is one example of an equilibrium reaction. The ratio between the polymer-forming ester group (-C(O)O-) and the condensation product water (H2O) against the acid-based (-C(O)OH) and alcohol-based (-OH) monomers is described by the equilibrium constant KC.
The equilibrium constant of the acid-alcohol based polyesterification is typically KC ≤ 10, what is not high enough to obtain high-molecular weight polymers (DPn ≥ 100), as the number average degree of polymerization (DPn) can be calculated from the equilibrium constant KC.[19]
In equilibrium reactions, it is therefore necessary to remove the condensation product continuously and efficiently from the reaction medium in order to drive the equilibrium towards polymer.[19] The condensation product is therefore removed at reduced pressure and high temperatures (150–320 °C, depending on the monomers) to prevent the back reaction.[8] With the progress of the reaction, the concentration of active chain ends is decreasing and the viscosity of the melt or solution increasing. For an increase of the reaction rate, the reaction is carried out at high end group concentration (preferably in the bulk), promoted by the elevated temperatures.
Equilibrium constants of magnitude KC ≥ 104 are achieved when using reactive reactants (
History
In 1926, United States–based
Biodegradation and environmental concerns
The
Cross-linking
Unsaturated polyesters are
Pollution of freshwater and seawater habitats
A team at Plymouth University in the UK spent 12 months analysing what happened when a number of synthetic materials were washed at different temperatures in domestic washing machines, using different combinations of detergents, to quantify the microfibres shed. They found that an average washing load of 6 kg could release an estimated 137,951 fibres from polyester-cotton blend fabric, 496,030 fibres from polyester and 728,789 from acrylic. Those fibers add to the general microplastics pollution.[32][33][34]
Safety
Fertility
Ahmed Shafik was a sexologist who won a Ig Nobel Prize on his research regarding how polyester can affect the fertility of rats,[35] dogs,[36] and men.[37]
Bisphenol A which is a endocrine disrupting chemical may be used in the synthesis of polyester.[38]
Recycling
See also
References
- ^ a b c d e Köpnick H, Schmidt M, Brügging W, Rüter J, Kaminsky W (June 2000). "Polyesters". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA.
- ISBN 9780743272865.
- ^ "Thermal Spray Abradable Coatings". www.gordonengland.co.uk. Retrieved 12 December 2018.
- ^ a b c d e f g h i j k l Rogers ME, Long TE (2003). Synthetic Methods in Step-Growth Polymers. Hoboken, New Jersey, US: John Wiley & Sons, Inc.
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- ^ Eveleth, R. and D. Chachra. Can Bees Make Tupperware? Scientific American December 19, 2011.
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- ISBN 978-3-527-30673-2, retrieved 13 December 2020
- ^ H.-G. Elias and R. Mülhaupt, in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany, 2015, pp. 1–70.
- ^ a b P. E. Cassidy, T. M. Aminabhavi and V. S. Reddy, in Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, Inc., Hoboken, New Jersey, US, 2000.
- ^ T. Whelan, Polymer Technology Dictionary, Springer Netherlands, Dordrecht, 1994.
- ^ Schuler MJ (1981). "Part 8: Dyeing with disperse dyes". Dyeing Primer. AATCC. p. 21. GGKEY:SK3T00EYAFR.
- ^ Ravve A (2012). Principles of Polymer Chemistry. New York, New York, NY: Springer.
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- ^ a b c d e Pilati F (1989). "Polyesters". Comprehensive Polymer Science and Supplements. Vol. 5. Elsevier. pp. 275–315.
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- ^ "How polyester is made - material, manufacture, making, history, used, structure, steps, product, History". www.madehow.com. Retrieved 4 December 2018.
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- ^ O'Connor MC (27 October 2014). "Inside the lonely fight against the biggest environmental problem you've never heard of". The Guardian.
- ^ Williams A (27 September 2016). "Washing clothes releases thousands of microplastic particles into environment, study shows". Plymouth University. Retrieved 9 October 2016.
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- ^ "Global plastic waste set to almost triple by 2060, says OECD". www.oecd.org. Retrieved 15 October 2022.
- ^ "How to keep a sustainable PET recycling industry in Europe - EPBP - European PET Bottle Platform". www.epbp.org. Retrieved 15 October 2022.
- ^ "Which Plastic Can Be Recycled?". Plastics For Change. Retrieved 15 October 2022.
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Further reading
- Textiles, by Sara Kadolph and Anna Langford. 8th Edition, 1998.
- Spinning Machines https://en.wikipedia.org/wiki/Spinning_(textiles)
External links