Polypropylene

Source: Wikipedia, the free encyclopedia.
Polypropylene (PP)
Polypropylene isotactic
Polypropylene syndiotactic
Names
IUPAC name
Poly(1-methylethylene)
Other names
Polypropylene; Polypropene;
Polipropene 25 [USAN]; Propene polymers;
Propylene polymers; 1-Propene; [-Ch2-Ch(Ch3)-]n
Identifiers
ChemSpider
  • None
ECHA InfoCard
 100.117.813 Edit this at Wikidata
UNII
Properties
(C3H6)n
Density 0.855 g/cm3, amorphous
0.946 g/cm3, crystalline
Melting point 130 to 171 °C (266 to 340 °F; 403 to 444 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Polypropylene (PP), also known as polypropene, is a

propylene
.

Polypropylene belongs to the group of polyolefins and is partially crystalline and non-polar. Its properties are similar to polyethylene, but it is slightly harder and more heat-resistant. It is a white, mechanically rugged material and has a high chemical resistance.[1]

Bio-PP is the

bio-based counterpart of polypropylene (PP).[2][3]

Polypropylene is the second-most widely produced commodity plastic (after polyethylene).

History

Phillips Petroleum chemists J. Paul Hogan and Robert Banks first demonstrated the polymerization of propylene in 1951.[4] The stereoselective polymerization to the isotactic was discovered by Giulio Natta and Karl Rehn in March 1954.[5] This pioneering discovery led to large-scale commercial production of isotactic polypropylene by the Italian firm Montecatini from 1957 onwards.[6] Syndiotactic polypropylene was also first synthesized by Natta. Interest in polypropylene development is ongoing to the present. For example, making polypropylene from bio-based resources is a topic of interest in the 21st century.[7]

Chemical and physical properties

Micrograph of polypropylene

Polypropylene is in little aspects similar to

solution behavior and electrical properties. The methyl group improves mechanical properties and thermal resistance, although the chemical resistance decreases.[8]: 19  The properties of polypropylene depend on the molecular weight and molecular weight distribution, crystallinity, type and proportion of comonomer (if used) and the isotacticity.[8] In isotactic polypropylene, for example, the methyl groups are oriented on one side of the carbon backbone. This arrangement creates a greater degree of crystallinity and results in a stiffer material that is more resistant to creep than both atactic polypropylene and polyethylene.[9]

Mechanical properties

The density of PP is between 0.895 and 0.93 g/cm3. Therefore, PP is the commodity plastic with the lowest density. With lower density, moldings parts with lower weight and more parts of a certain mass of plastic can be produced. Unlike polyethylene, crystalline and amorphous regions differ only slightly in their density. However, the density of polyethylene can significantly change with fillers.[8]: 24 

The Young's modulus of PP is between 1300 and 1800 N/mm².

Polypropylene is normally tough and flexible, especially when copolymerized with ethylene. This allows polypropylene to be used as an engineering plastic, competing with materials such as acrylonitrile butadiene styrene (ABS). Polypropylene is reasonably economical.[citation needed]

Polypropylene has good resistance to fatigue.[10]: 3070 

Thermal properties

The melting point of polypropylene occurs in a range, so the melting point is determined by finding the highest temperature of a

Syndiotactic PP with a crystallinity of 30% has a melting point of 130 °C (266 °F).[10] Below 0 °C, PP becomes brittle.[11]

The thermal expansion of PP is significant, but somewhat less than that of polyethylene. [11]

Chemical properties

Polypropylene at room temperature is resistant to fats and almost all organic

Markovnikov rule).[12]

Most commercial polypropylene is

isotactic and has an intermediate level of crystallinity between that of low-density polyethylene (LDPE) and high-density polyethylene
(HDPE). Isotactic & atactic polypropylene is soluble in p-xylene at 140 °C. Isotactic precipitates when the solution is cooled to 25 °C and atactic portion remains soluble in p-xylene.

The melt flow rate (MFR) or melt flow index (MFI) is a measure of molecular weight of polypropylene. The measure helps to determine how easily the molten raw material will flow during processing. Polypropylene with higher MFR will fill the plastic mold more easily during the injection or blow-molding production process. As the melt flow increases, however, some physical properties, like impact strength, will decrease.

There are three general types of polypropylene:

EPDM
added to polypropylene homopolymer increases its low temperature impact strength. Randomly polymerized ethylene monomer added to polypropylene homopolymer decreases the polymer crystallinity, lowers the melting point and makes the polymer more transparent.

Molecular structure – tacticity

Polypropylene can be categorized as atactic polypropylene (aPP), syndiotactic polypropylene (sPP) and isotactic polypropylene (iPP). In case of atactic polypropylene, the methyl group (-CH3) is randomly aligned, alternating (alternating) for syndiotactic polypropylene and evenly for isotactic polypropylene. This has an impact on the crystallinity (amorphous or semi-crystalline) and the thermal properties (expressed as

glass transition point Tg and melting point
Tm).

The term

semi-crystalline polymer. The higher the isotonicity(the isotactic fraction), the greater the crystallinity, and thus also the softening point, rigidity, e-modulus and hardness.[8]
: 22 

Atactic polypropylene, on the other hand, lacks any regularity which makes it unable to crystallize and amorphous.

Crystal structure of polypropylene

Isotactic polypropylene has a high degree of crystallinity, in industrial products 30–60%. Syndiotactic polypropylene is slightly less crystalline, atactic PP is amorphous (not crystalline).[13]: 251 

Isotactic polypropylene (iPP)

Is polypropylene can exist in various crystalline modifications which differ by the molecular arrangement of the polymer chains. The crystalline modifications are categorized into the α-, β- and γ-modification as well as mesomorphic (smectic) forms.[14] The α-modifications is predominant in iPP. Such crystals are built from lamellae in the form of folded chains. A characteristic anomaly is that the lame are arranged in the so-called "cross-hatched" structure.[15] The melting point of α-crystalline regions is given as 185[16][17] to 220 °C,[16][18] the density as 0.936 to 0.946 g·cm−3.[19][20] The β-modification is in comparison somewhat less ordered, as a result of which it forms faster[21][22] and has a lower melting point of 170 to 200 °C.[16][23][24][18] The formation of the β-modification can be promoted by nucleating agents, suitable temperatures and shear stress.[21][25] The γ-modification is hardly formed under the conditions used in industry and is poorly understood. The mesomorphic modification, however, occurs often in industrial processing, since the plastic is usually cooled quickly. The degree of order of the mesomorphic phase ranges between the crystalline and the amorphous phase, its density is with 0.916 g·cm−3 comparatively. The mesomorphic phase is considered as cause for the transparency in rapidly cooled films (due to low order and small crystallites).[13]

Syndiotactic polypropylene (sPP)

Syndiotactic polypropylene was discovered much later than isotactic PP and could only be prepared by using

metallocene catalysts. Syndiotactic PP has a lower melting point, with 161 to 186 °C, depending on the degree of tacticity.[26][27][28]

Atactic polypropylene (aPP)

Atactic polypropylene is amorphous and has therefore no crystal structure. Due to its lack of crystallinity, it is readily soluble even at moderate temperatures, which allows to separate it as by-product from isotactic polypropylene by extraction. However, the aPP obtained this way is not completely amorphous but can still contain 15% crystalline parts. Atactic polypropylene can also be produced selectively using metallocene catalysts, atactic polypropylene produced this way has a considerably higher molecular weight.[13]

Atactic polypropylene has lower density, melting point and softening temperature than the crystalline types and is tacky and rubber-like at room temperature. It is a colorless, cloudy material and can be used between −15 and +120 °C. Atactic polypropylene is used as a sealant, as an

automobiles and as an additive to bitumen.[29]

Copolymers

Polypropylene

random copolymer with polyethylene used for plastic pipework
.

PP-RCT

Polypropylene random crystallinity temperature (PP-RCT), also used for plastic pipework, is a new form of this plastic. It achieves higher strength at high temperature by β-crystallization.[30]

Degradation

Effect of UV exposure on polypropylene rope

Polypropylene is liable to chain degradation from exposure to temperatures above 100 °C. Oxidation usually occurs at the

anti-oxidants such as phosphites (e.g. tris(2,4-di-tert-butylphenyl)phosphite) and hindered phenols, which prevent polymer degradation.[1]

Microbial communities isolated from soil samples mixed with starch have been shown to be capable of degrading polypropylene.[31] Polypropylene has been reported to degrade while in the human body as implantable mesh devices. The degraded material forms a tree bark-like layer at the surface of mesh fibers.[32]

Optical properties

PP can be made

acrylic, or certain other plastics. It is often opaque
or colored using pigments.

Production

Polypropylene is produced by the

propene
:

The industrial production processes can be grouped into gas phase polymerization, bulk polymerization and slurry polymerization. All state-of-the-art processes use either gas-phase or bulk reactor systems.[1]

The properties of PP are strongly affected by its tacticity, the orientation of the methyl groups (CH
3) relative to the methyl groups in neighboring monomer units (see above). The tacticity of polypropylene can be chosen by the choice of an appropriate catalyst.

Catalysts

The properties of PP are strongly affected by its tacticity, the orientation of the methyl groups (CH
3 in the figure) relative to the methyl groups in neighboring monomer units. A Ziegler–Natta catalyst is able to restrict linking of monomer molecules to a specific orientation, either isotactic, when all methyl groups are positioned at the same side with respect to the backbone of the polymer chain, or syndiotactic, when the positions of the methyl groups alternate. Commercially available isotactic polypropylene is made with two types of Ziegler-Natta catalysts. The first group of the catalysts encompasses solid (mostly supported) catalysts and certain types of soluble metallocene catalysts. Such isotactic macromolecules coil into a helical shape; these helices then line up next to one another to form the crystals that give commercial isotactic polypropylene many of its desirable properties.

A ball-and-stick model of syndiotactic polypropylene

Another type of metallocene catalysts produce syndiotactic polypropylene.[26] These macromolecules also coil into helices (of a different type) and crystallize. Atactic polypropylene is an amorphous rubbery material. It can be produced commercially either with a special type of supported Ziegler-Natta catalyst or with some metallocene catalysts.

Modern supported Ziegler-Natta catalysts developed for the polymerization of propylene and other

1-alkenes to isotactic polymers usually use TiCl
4 as an active ingredient and MgCl
2 as a support.[33][34][35]
The catalysts also contain organic modifiers, either aromatic acid esters and diesters or ethers. These catalysts are activated with special cocatalysts containing an organoaluminum compound such as Al(C2H5)3 and the second type of a modifier. The catalysts are differentiated depending on the procedure used for fashioning catalyst particles from MgCl2 and depending on the type of organic modifiers employed during catalyst preparation and use in polymerization reactions. Two most important technological characteristics of all the supported catalysts are high productivity and a high fraction of the crystalline isotactic polymer they produce at 70–80 °C under standard polymerization conditions. Commercial synthesis of isotactic polypropylene is usually carried out either in the medium of liquid propylene or in gas-phase reactors.

Commercial synthesis of syndiotactic polypropylene is carried out with the use of a special class of metallocene catalysts. They employ bridged bis-metallocene complexes of the type bridge-(Cp1)(Cp2)ZrCl2 where the first Cp ligand is the cyclopentadienyl group, the second Cp ligand is the fluorenyl group, and the bridge between the two Cp ligands is -CH2-CH2-, >SiMe2, or >SiPh2.[36] These complexes are converted to polymerization catalysts by activating them with a special organoaluminum cocatalyst, methylaluminoxane (MAO).[37]

Manufacturing from polypropylene

Melting process of polypropylene can be achieved via extrusion and molding. Common extrusion methods include production of melt-blown and spun-bond fibers to form long rolls for future conversion into a wide range of useful products, such as face masks, filters, diapers and wipes.

The most common shaping technique is

injection-stretch blow molding
are also used, which involve both extrusion and molding.

The large number of end-use applications for polypropylene are often possible because of the ability to tailor grades with specific molecular properties and additives during its manufacture. For example,

antistatic additives can be added to help polypropylene surfaces resist dust and dirt. Many physical finishing techniques can also be used on polypropylene, such as machining. Surface treatments
can be applied to polypropylene parts in order to promote adhesion of printing ink and paints.

Expanded Polypropylene (EPP) has been produced through both solid and melt state processing. EPP is manufactured using melt processing with either chemical or physical blowing agents. Expansion of PP in solid state, due to its highly crystalline structure, has not been successful. In this regard, two novel strategies were developed for expansion of PP. It was observed that PP can be expanded to make EPP through controlling its crystalline structure or through blending with other polymers.[38][39]

Biaxially oriented polypropylene (BOPP)

When polypropylene film is extruded and stretched in both the machine direction and across machine direction it is called biaxially oriented polypropylene. Two methods are widely used for producing BOPP films, namely, the tender process and tubular process.

converting. It is normally produced in large rolls which are slit on slitting machines into smaller rolls for use on packaging machines. BOPP is also used for stickers and labels[42]
in addition to OPP. It is non-reactive which makes BOPP suitable for safe use in the pharmaceutical and food industry. It is one of the most important commercial polyolefin films. BOPP films are available in different thicknesses and widths. They are transparent and flexible.

Applications

Polypropylene lid of a Tic Tac box, with a living hinge and the resin identification code under its flap

As polypropylene is resistant to fatigue, most plastic living hinges, such as those on flip-top bottles, are made from this material. However, it is important to ensure that chain molecules are oriented across the hinge to maximise strength.

Polypropylene is used in the manufacturing of

hydronic heating and cooling, and reclaimed water).[43] This material is often chosen for its resistance to corrosion and chemical leaching, its resilience against most forms of physical damage, including impact and freezing, its environmental benefits, and its ability to be joined by heat fusion rather than gluing.[44][45][46]

A polypropylene chair

Many plastic items for medical or laboratory use can be made from polypropylene because it can withstand the heat in an autoclave. Its heat resistance also enables it to be used as the manufacturing material of consumer-grade kettles[citation needed]. Food containers made from it will not melt in the dishwasher, and do not melt during industrial hot filling processes. For this reason, most plastic tubs for dairy products are polypropylene sealed with aluminum foil (both heat-resistant materials). After the product has cooled, the tubs are often given lids made of a less heat-resistant material, such as LDPE or polystyrene. Such containers provide a good hands-on example of the difference in modulus, since the rubbery (softer, more flexible) feeling of LDPE with respect to polypropylene of the same thickness is readily apparent. Rugged, translucent, reusable plastic containers made in a wide variety of shapes and sizes for consumers from various companies such as Rubbermaid and Sterilite are commonly made of polypropylene, although the lids are often made of somewhat more flexible LDPE so they can snap onto the container to close it. Polypropylene can also be made into disposable bottles to contain liquid, powdered, or similar consumer products, although HDPE and polyethylene terephthalate are commonly also used to make bottles. Plastic pails, car batteries, wastebaskets, pharmacy prescription bottles, cooler containers, dishes and pitchers are often made of polypropylene or HDPE, both of which commonly have rather similar appearance, feel, and properties at ambient temperature. An abundance of medical devices are made from PP.[47]

Polypropylene items for laboratory use. Blue and orange closures are not made of polypropylene.

A common application for polypropylene is as biaxially oriented polypropylene (BOPP). These BOPP sheets are used to make a wide variety of materials including clear bags. When polypropylene is biaxially oriented, it becomes crystal clear and serves as an excellent packaging material for artistic and retail products.

Polypropylene, highly colorfast, is widely used in manufacturing carpets, rugs and mats to be used at home.[48]

Polypropylene is widely used in ropes, distinctive because they are light enough to float in water.[49] For equal mass and construction, polypropylene rope is similar in strength to polyester rope. Polypropylene costs less than most other synthetic fibers.

Polypropylene is also used as an alternative to

LSZH
cable in low-ventilation environments, primarily tunnels. This is because it emits less smoke and no toxic halogens, which may lead to production of acid in high-temperature conditions.

Polypropylene is also used in particular roofing membranes as the waterproofing top layer of single-ply systems as opposed to modified-bit systems.

Polypropylene is most commonly used for plastic moldings, wherein it is injected into a mold while molten, forming complex shapes at relatively low cost and high volume; examples include bottle tops, bottles, and fittings.

It can also be produced in sheet form, widely used for the production of stationery folders, packaging, and storage boxes. The wide color range, durability, low cost, and resistance to dirt make it ideal as a protective cover for papers and other materials. It is used in Rubik's Cube stickers because of these characteristics.

The availability of sheet polypropylene has provided an opportunity for the use of the material by designers. The light-weight, durable, and colorful plastic makes an ideal medium for the creation of light shades, and a number of designs have been developed using interlocking sections to create elaborate designs.

Polypropylene fibres are used as a

spalling.[50] In some areas susceptible to earthquakes (e.g., California), PP fibers are added with soils to improve the soil's strength and damping when constructing the foundation of structures such as buildings, bridges, etc.[51]

Clothing

Various polypropylene yarns and textiles

Polypropylene is a major polymer used in

nonwovens, with over 50% used[citation needed] for diapers or sanitary products where it is treated to absorb water (hydrophilic) rather than naturally repelling water (hydrophobic). Other non-woven uses include filters for air, gas, and liquids in which the fibers can be formed into sheets or webs that can be pleated to form cartridges or layers that filter in various efficiencies in the 0.5 to 30 micrometre range. Such applications occur in houses as water filters or in air-conditioning-type filters. The high surface-area and naturally oleophilic polypropylene nonwovens are ideal absorbers of oil spills with the familiar[citation needed
] floating barriers near oil spills on rivers.

Polypropylene, or 'polypro', has been used for the fabrication of cold-weather base layers, such as long-sleeve shirts or long underwear. Polypropylene is also used in warm-weather clothing, in which it transports sweat away from the skin. Polyester has replaced polypropylene in these applications in the U.S. military, such as in the ECWCS.[52] Although polypropylene clothes are not easily flammable, they can melt, which may result in severe burns if the wearer is involved in an explosion or fire of any kind.[53] Polypropylene undergarments are known for retaining body odors which are then difficult to remove. The current generation of polyester does not have this disadvantage.[54]

Medical

Its most common medical use is in the synthetic, nonabsorbable

Ethicon Inc.

Polypropylene has been used in hernia and pelvic organ prolapse repair operations to protect the body from new hernias in the same location. A small patch of the material is placed over the spot of the hernia, below the skin, and is painless and rarely, if ever, rejected by the body. However, a polypropylene mesh will erode the tissue surrounding it over the uncertain period from days to years.

A notable application was as a transvaginal mesh, used to treat vaginal prolapse and concurrent urinary incontinence.[55] Due to the above-mentioned propensity for polypropylene mesh to erode the tissue surrounding it, the FDA has issued several warnings on the use of polypropylene mesh medical kits for certain applications in pelvic organ prolapse, specifically when introduced in close proximity to the vaginal wall due to a continued increase in number of mesh-driven tissue erosions reported by patients over the past few years.[56] On 3 January 2012, the FDA ordered 35 manufacturers of these mesh products to study the side effects of these devices. Due to the outbreak of the COVID-19 pandemic in 2020, the demand for PP has increased significantly because it's a vital raw material for producing meltblown fabric, which is in turn the raw material for producing facial masks.

Recycling

Polypropylene has "5" as its resin identification code:[57]

Repairing

PP objects can be joined with a

two-part epoxy glue or using hot-glue guns.[58]

PP can be melted using a

speed tip welding
technique. With speed welding, the plastic welder, similar to a soldering iron in appearance and wattage, is fitted with a feed tube for the plastic weld rod. The speed tip heats the rod and the substrate, while at the same time it presses the molten weld rod into position. A bead of softened plastic is laid into the joint and the parts and weld rod fuse. With polypropylene, the melted welding rod must be "mixed" with the semi-melted base material being fabricated or repaired. A speed tip "gun" is essentially a soldering iron with a broad, flat tip that can be used to melt the weld joint and filler material to create a bond.

Health concerns

The advocacy organization Environmental Working Group classifies PP as of low to moderate hazard.[59][why?] PP is

dope-dyed; no water is used in its dyeing, in contrast with cotton.[60]

Combustibility

Like all organic compounds, polypropylene is combustible.[61] The flash point of a typical composition is 260 °C; autoignition temperature is 388 °C.[62]

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