Cobalt glass

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Smalt
 
CIELChuv (L, C, h)
(26, 74, 261°)
SourceColorHexa[1]
B: Normalized to [0–255] (byte)
Cobalt glass for decoration

Cobalt glass—known as "smalt" when ground as a pigment—is a deep blue coloured

cobalt carbonate
, in a glass melt. Cobalt is a very intense colouring agent and very little is required to show a noticeable amount of colour.

Cobalt glass plates are used as an optical

filter in flame tests to filter out the undesired strong yellow light emitted by traces of sodium, and expand the ability to see violet and blue hues,[2] similar to didymium glass. Specialty tasting glasses made of cobalt glass are used by professional olive oil tasters to disguise the color of the oil being assessed to avoid bias in judging. [3]

Regulation cobalt blue olive oil tasting glass with watch glass cover

Moderately ground cobalt glass (potassium cobalt silicate)—called "smalt"—has been historically important as a pigment in glassmaking, painting, pottery, for surface decoration of other types of glass and ceramics, and other media.[4][5] The long history of its manufacture and use has been described comprehensively.[6] Cobalt aluminate, also known as "cobalt blue",[7] can be used in a similar way.

Cobalt glass such as

Harvey's Bristol Cream sherry and Tŷ Nant
mineral water.

Ming dish, with smalt blue decoration

History

intaglio of the figure of Victory

The earliest known example of

blue and white porcelain from the Yuan and Ming dynasties, Renaissance Italian maiolica and Delftware.[8]

Samples of smalt in the Historical dye collection of the Technical University of Dresden, Germany

frescos of Domenico Ghirlandaio (1449–1494).[11][12]

The invention of a European smalt process has traditionally been credited to a Bohemian glassmaker named Christoph Schürer, around 1540–1560.[13] However, its presence in Dieric Bouts' The Entombment from circa 1455 proves that it was used at least a century earlier.[14]

In England and Scotland, smalt was added to laundry starch. James VI and I considered awarding a patent for making a "blue azure" product for this purpose in Scotland in February 1609.[15]

The process used for producing cobalt smalt glass at the Blaafarveværket industrial manufacturing center in Norway in the 19th century has been documented as smelting cobalt oxide together with quartz and potassium carbonate. The result was an intensely blue glass-like substance that was ground and sold to producers of glassware and porcelain.[16]

Notes

  1. ^ "Smalt / #003399 hex color (#039)". ColorHexa. Retrieved 2022-12-22.
  2. ^ Glass Plates, Cobalt, Flinn Scientific
  3. ^ [1], Olive Oil Times
  4. ^ a b "The Changing Properties of Smalt Over Time". Tate. Retrieved December 26, 2020.
  5. .
  6. ^ "Cobalt". Encyclopædia Iranica. Retrieved December 26, 2020.
  7. ^ a b Encyclopedia Iranica, "Cobalt"
  8. JSTOR 4629297
    .
  9. ^ Jules Marie J. Guiffrey; Léon Emmanuel S.J. Laborde (marq. de) (1877). J.M.J. Guiffrey (ed.). Les comptes des bâtiments du roi, 1528–1571. Suivis de documents inéd. sur les châteaux royaux et les beaux-arts au XVIE siècle, recueillis par le marq. L. de Laborde (in French). Paris. p. 96. Retrieved 6 November 2010.{{cite book}}: CS1 maint: location missing publisher (link)
  10. ^ See: (1) Mauro Bacci and Marcello Picollo, "Non-Destructive Spectroscopic Detection of Cobalt(II) in Paintings and Glass," Studies in Conservation, vol. 41, no. 3, pages 136–144 (1996); especially page 136; and (2) C. Altavilla and E. Ciliberto, "Decay characteristics of glassy pigments: an XPS investigation of smalt paint layers," Applied Physics A, vol. 79, pages 309–314 (2004); especially page 309.
  11. ^ See also: Bruno Mühlethaler and Jean Thissen, "Smalt," pages 113–130 in Ashok Roy, ed., Artists' Pigments: A Handbook of Their History and Characteristics, vol. 2 (Oxford, England: Oxford University Press, 1997).
  12. . Retrieved 6 November 2010.
  13. ^ B. Mühlethaler and J. Thyssen, "Smalt", In : A.Roy [ed.], Artist's Pigments: A handbook of Their Characteristics, volume 2, 1993, p. 113-130
  14. ^ David Masson, Register of the Privy Council of Scotland, 1607-1610, vol. 8 (Edinburgh, 1887), p. 559.
  15. . Retrieved 6 November 2010.

Further reading

  1. An Archaeometallurgical Explanation for the Disappearance of Egyptian and Near Eastern Cobalt-Blue Glass at the end of the Late Bronze Age, Jonathan, R. Wood and Hsu Yi-Ting, 2019, Internet Archaeology 52, Internet Archaeology
  2. Smalt, Bruno Mühlethaler and Jean Thissen, Studies in Conservation, Vol. 14, No. 2 (May, 1969), pp. 47–61, JSTOR

External links

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