Stannane
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Names | |||
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IUPAC name
Stannane
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Other names
tin tetrahydride
tin hydride | |||
Identifiers | |||
3D model (
JSmol ) |
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ChEBI | |||
ChemSpider | |||
PubChem CID
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CompTox Dashboard (EPA)
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Properties | |||
SnH4 | |||
Molar mass | 122.71 g/mol | ||
Appearance | colourless gas | ||
Density | 5.4 g/L, gas | ||
Melting point | −146 °C (−231 °F; 127 K) | ||
Boiling point | −52 °C (−62 °F; 221 K) | ||
Structure | |||
Tetrahedral | |||
0 D | |||
Thermochemistry | |||
Heat capacity (C)
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1.262 kJ/(kg·K) | ||
Std enthalpy of (ΔfH⦵298)formation |
162.8 kJ/mol | ||
Enthalpy of vaporization (ΔfHvap)
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19.049 kJ/mol | ||
Related compounds | |||
Related
organotins |
tributylstannane (Bu3SnH) | ||
Related compounds
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Methane Silane Germane Plumbane | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Stannane
- SnCl4 + Li[AlH4] → SnH4 + LiCl + AlCl3
Stannane decomposes slowly at room temperature to give metallic tin and hydrogen and ignites on contact with air.[1]
Variants of stannane can be found as a highly
inorganic metal hydrides and group 14 hydrides
.
See also
- Organotin
References
- ^ ISBN 978-0-08-037941-8.