Sulfur monoxide
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Names | |||
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IUPAC name
Sulfur monoxide[citation needed]
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Systematic IUPAC name
Oxidosulfur[1] | |||
Identifiers | |||
3D model (
JSmol ) |
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7577656 | |||
ChEBI | |||
ChEMBL | |||
ChemSpider | |||
666 | |||
MeSH | sulfur+monoxide | ||
PubChem CID
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CompTox Dashboard (EPA)
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Properties | |||
SO | |||
Molar mass | 48.064 g mol−1 | ||
Appearance | Colourless gas | ||
Reacts | |||
log P | 0.155 | ||
Thermochemistry | |||
Std molar
entropy (S⦵298) |
221.94 J K−1 mol−1 | ||
Std enthalpy of (ΔfH⦵298)formation |
5.01 kJ mol−1 | ||
Related compounds | |||
Related compounds
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Triplet oxygen Disulfur | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Sulfur monoxide is an inorganic compound with formula SO. It is only found as a dilute gas phase. When concentrated or condensed, it converts to S2O2 (disulfur dioxide). It has been detected in space but is rarely encountered intact otherwise.
Structure and bonding
The SO molecule has a triplet ground state similar to
The molecule is excited with
Production and reactions
Production of SO as a reagent in organic syntheses has centred on using compounds that "extrude" SO. Examples include the decomposition of the relatively simple molecule ethylene episulfoxide:[4] as well as more complex examples, such as a trisulfide oxide, C10H6S3O.[5]
- C2H4SO → C2H4 + SO
The SO molecule is thermodynamically unstable, converting initially to S2O2.[2] SO inserts into
Generation under extreme conditions
In the laboratory, sulfur monoxide can be produced by treating sulfur dioxide with sulfur vapor in a glow discharge.[2] It has been detected in single-bubble sonoluminescence of concentrated sulfuric acid containing some dissolved noble gas.[7]
Benner and Stedman developed a chemiluminescence detector for sulfur via the reaction between sulfur monoxide and ozone:[8]
- SO + O3 → SO2* + O2
- SO2* → SO2 + hν
(* indicates an excited state)
Occurrence
Ligand for transition metals
As a ligand SO can bond in a number different ways:[9][10]
- a terminal ligand, with a bent M−O−S arrangement, for example with titanium oxyfluoride[11]
- a terminal ligand, with a bent M−S−O arrangement, analogous to bent nitrosyl
- bridging across two or three metal centres (via sulfur), as in Fe3(μ3-S)(μ3-SO)(CO)9
- η2 sideways-on (d–π interaction) with vanadium, niobium, and tantalum.[12]
Astrochemistry
Sulfur monoxide has been detected around Io, one of Jupiter's moons, both in the atmosphere[13] and in the plasma torus.[14] It has also been found in the atmosphere of Venus,[15] in Comet Hale–Bopp,[16] in 67P/Churyumov–Gerasimenko,[17] and in the interstellar medium.[18]
On Io, SO is thought to be produced both by volcanic and photochemical routes. The principal photochemical reactions are proposed as follows:[19]
- O + S2 → S + SO
- SO2 → SO + O
Sulfur monoxide has been found in NML Cygni.[20]
Biological chemistry
Sulfur monoxide may have some biological activity. The formation of transient SO in the
Safety measures
Because of sulfur monoxide's rare occurrence in our atmosphere and poor stability, it is difficult to fully determine its hazards. But when condensed and compacted, it forms disulfur dioxide, which is relatively toxic and corrosive. This compound is also highly flammable (similar flammability to methane) and when burned produces sulfur dioxide, a poisonous gas.
Sulfur monoxide dication
- C6(CH3)6 + SO2 + 3 HF·AsF5 → [C6(CH3)6SO][AsF6]2 + [H3O][AsF6]
Disulfur dioxide
SO converts to disulfur dioxide (S2O2).
References
- ^ "sulfur monoxide (CHEBI:45822)". Chemical Entities of Biological Interest. UK: European Bioinformatics Institute.
- ^ ISBN 978-0-08-037941-8.
- .
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- PMID 11678709.
- PMID 17506566.
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- S2CID 98849015.
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- ISBN 0-471-93620-0.
- S2CID 201617509.
- S2CID 73438027.
- .
- PMID 10720321.
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- S2CID 51862359.
- ^ "Астрономический вестник. T. 54, Номер 2, 2020".
- doi:10.1086/155757.
- .
- ISBN 978-1-58112-061-5. Retrieved 23 August 2012.
- PMID 14623333.
- S2CID 27260554.
- ^ .