Zirconium(III) chloride
Names | |
---|---|
IUPAC name
Zirconium trichloride
| |
Identifiers | |
3D model (
JSmol ) |
|
ChemSpider | |
PubChem CID
|
|
| |
| |
Properties | |
Cl3Zr | |
Molar mass | 197.57 g·mol−1 |
Appearance | Blue-black crystals |
Density | 3.05 g/cm3[1] |
Melting point | 627 °C (1,161 °F; 900 K) at 760 mmHg[1] |
Reacts[1] | |
Solubility | Soluble in benzene, CS2 |
Structure | |
P63/mcm, No. 193[2] | |
6/m 2/m 2/m[2] | |
a = 6.36 Å, c = 6.14 Å[2] α = 90°, β = 90°, γ = 120°
| |
Thermochemistry | |
Heat capacity (C)
|
96.21 J/mol·K[3] |
Std molar
entropy (S⦵298) |
145.79 J/mol·K[3] |
Std enthalpy of (ΔfH⦵298)formation |
−714.21 kJ/mol[3] |
Related compounds | |
Other anions
|
Zirconium(III) bromide Zirconium(III) iodide |
Other cations
|
Titanium(III) chloride Hafnium(III) chloride |
Related compounds
|
Zirconium(IV) chloride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|
Zirconium(III) chloride is an
Preparation
The material was first claimed by
- Zr + 3 ZrCl4 → 4 ZrCl3
When aluminium is used as the reducing agent with zirconium tetrachloride, a series of choloroaluminates are formed, for example [Zr(AlCl4)2(AlCl4)2] and Zr(AlCl4)3.[6]
Since the trihalides, such as zirconium trichloride, are comparatively nonvolatile, contamination can be avoided by using a gaseous reductant. For example, zirconium trichloride can be prepared by reduction of zirconium tetrachloride with hydrogen.[7]
- ZrCl4 + ½ H2 → ZrCl3 + HCl
Structure
Some zirconium halides (ZrCl3, ZrBr3, and ZrI3) have structures similar to HfI3. They also have similar space group (P63/mcm) and hexagonal structure with 2 molecules in the cell.[2] The magnetic susceptibility of zirconium trichloride suggests metal-metal interactions of the unpaired electron on each Zr(III) center. The magnetic moment of ZrCl3 (0.4 BM) indicates considerable overlap of metal orbitals.[8]
References
- ^ ISBN 978-1-4200-9084-0.
- ^ ISBN 978-0-387-26147-8.
- ^ a b c Zirconium chloride in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD) (retrieved 2014-06-23)
- .
- .
- .
- .
- ^ Wells, A.F. Structural Inorganic Chemistry. Oxford Science Publications, 1975, 5th ed, 417-420.