Cationization of cotton

Cationization of cotton is an electro kinetic phenomena ( zeta potential and electro kinetic) for surface charge of cotton. The cotton surface is charged with negative ions. Cationization alters the characterization of the surface of the cotton which allows salt free dyeing and improves the dye ability of cotton. The process involves the chemical reaction of cationic reactive agents with cellulose.^[1][2][3]

Etymology

A cation (+) (/ˈkætˌaɪ.ən/), from the Greek word κάτω (káto), meaning "down", is an ion with fewer electrons than protons, giving it a positive charge. The suffixes for cationic groups discern between 'ylium' for cations created by the loss of a hydride ion and 'ium' for cations formed by addition of a Hydron.^[4]

Methods of cationization

Cationization involves the modification of cellulosic macromolecules with positively charged sites with chemical reaction of cationic reactive agents for example with Quaternary ammonium cation or using (3-chloro-2-hydroxylpropyl) trimethyl-ammonium chloride (CHPTAC).^[5][6]

Advantages

Cotton possesses a negative surface charge, while reactive and direct dyes also carry a negative charge. The like charges repel each other, and the addition of salt aids in dyeing by generating a positive charge on the cotton surface.^[7][8] The industry has predominantly used reactive dyes to color knitted cotton goods. The treatment of salt-laden, colored effluent generated by the dyeing process is one of the industry's primary concerns. Cotton cationization is one of the most effective solutions to the aforementioned problem.^[9]

Cationization of cotton enables salt free dyeing and enhances the dyeability of the substrate with anionic dyes such as

• Quaternary ammonium cation

References