Dicarbollide

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Dicarbollide

Numbering system for nido-11 vertex clusters.
Identifiers
3D model (
JSmol
)
  • InChI=1S/C2H11B9/c1-2-4-5-3(1)7(1)6(1,2)8(2,4)10(4,5)9(3,5,7)11(6,7,8)10/h1-11H/q-2
    Key: JVDACFRPVHVFFP-UHFFFAOYSA-N
  • [B-H]1234[BH]5%12%13[B-H]1%10%11[BH]289[BH]367[BH]145[BH]6%14[BH]78[BH]9%10[CH]%11%12[CH]1%13%14
Properties
C2H11B9−
Molar mass 132.40 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

In

ortho-carborane.[1] These dianions function as ligands, related to the cyclopentadienyl anion
. Substituted dicarbollides are also known such as [C2B9H10(pyridine)]− (pyridine bonded to B) and [C2R2B9H9]2- (R groups bonded to carbon).

Synthesis of dicarbollides

Dicarbollides are obtained by base-degradation of 12-vertex dicarboranes. This degradation of the ortho derivative has been most heavily studied. The conversion is conducted in two-steps, first "deboronation" and second deprotonation:[2]

Reversible redox chemistry of Ni(III)/Ni(IV) bis(dicarbollide) clusters.
Reversible redox chemistry of Ni(III)/Ni(IV) bis(dicarbollide) clusters
C2B10H12 + NaOEt + 2 EtOH → Na+C2B9H12− + H2 + B(OEt)3
Na+C2B9H12− + NaH → Na2C2B9H11 + H2

The dianion derived from dicarboranes, [C2B9H11]2-, are nido clusters. Three isomers exist. Most commonly studies is the 7,8-isomer, with two adjacent carbon centers on the rim. 7,9-C2B9H2−11 has non-adjacent carbon centers on the rim. It is derived by degradation of meta-C2B10H12. 2,9-C2B9H2−11 has only one carbon center on the rim. It is derived by degradation of para-C2B10H12.[3]

Coordination compounds

Structure of (Me4N+)2[Fe(C2B9H11)2]2-, showing only one Me4N+.[4]

A variety of complexes - a subset of metallaborane - are known with one or two dicarbollide ligands. An example of a 1:1 complex is [Mn(CO)3(η5-7,8-C2B9H11)]−.[5]

Most heavily studied are complexes with two dicarbollide ligands, especially

sandwich complexes. Thus, these are prepared by salt metathesis reactions, as illustrated by the synthesis of the ferrocene
analogue:

2 Na2C2B8H11 + FeCl2 → Na2[Fe(C2B8H11)2] + 2 NaCl

These bisdicarbollide dianions are often readily oxidized. Fe(III), Co(III), Ni(III), and Ni(IV) derivatives are known. In some cases, the oxidation induces rearrangement of the C2B9 cage to give complexes where the carbon centers are nonadjacent.[1]

Precursor to other carboranes

Diprotonation of [C2B9H11]2− gives the neutral carborane C2B9H13. Pyrolysis of this nido cluster gives closo-C2B9H11. Chromate-oxidation of [C2B9H12]− results in deboronation, giving the C2B7H13. This carborane features two CH2 vertices.[6]

Homogeneous catalysis

The clam-shell dicarbollide complex (Cp*)(C2B9H11)ZrCH3 catalyzes alkene polymerization.[7]

References

  1. ^
    doi:10.1016/S0022-328X(00)00610-0
    .
  2. ISBN 978-0-470-13253-1
    .
  3. doi:10.1039/B108937D
    .
  4. doi:10.1021/ic00009a015
    .
  5. doi:10.1021/om049822l
    .
  6. ISBN 978-0-12-801894-1
    .
  7. doi:10.1021/ja00004a080
    .
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