Hummers' method

Hummers' method is a chemical process that can be used to generate

.

Graphite oxide

Graphite oxide is a compound of carbon, oxygen, and hydrogen where there is a ratio between 2.1 and 2.9 of carbon to oxygen. Graphite oxide is typically a yellowish solid. It is also known as graphene oxide when used to form unimolecular sheets.

Method

Hummers' method^[1] was developed in 1958 as a safer, faster and more efficient method of producing graphite oxide. Before the method was developed, the production of graphite oxide was slow and hazardous to make because of the use of concentrated sulfuric and nitric acid. The Staudenmeier–Hoffman–Hamdi method^[2] introduced the addition of potassium chlorate. However, this method had more hazards and produced one gram of graphite oxide to ten grams of potassium chlorate.^[3]

. Their approach was similar in that it involved adding graphite to a solution of concentrated acid. However, they simplified it to just graphite, concentrated sulfuric acid, sodium nitrate, and potassium permanganate. They also did not have to use temperatures above 98 °C and avoided most of the explosive risk of the Staudenmeier–Hoffman–Hamdi method.

The procedure starts with 100 g graphite and 50 g of sodium nitrate in 2.3 liters of sulfuric acid at 66 °C which is then cooled to 0 °C. 300 g of potassium permanganate is then added to the solution and stirred. Water is then added in increments until the solution is approximately 32 liters.

The final solution contains about 0.5% of solids to then be cleaned of impurities and dehydrated with phosphorus pentoxide.

Chemical equations and efficiency

The basic chemical reaction involved in the Hummers' method is the

are evolved in the process. The final product is typically 47.06% carbon, 27.97% oxygen, 22.99% water, and 1.98% ash with a carbon-to-oxygen ratio of 2.25. All of these results are comparable to the methods that preceded them.

A comparison of Hummers method to the Staudenmeier method^[1]

Method	% Carbon	% Oxygen	% Water	% Ash	Carbon-to-oxygen atomic ratio
Hummers	47.06	27.97	22.99	1.98	2.25
Staudenmeier	52.112	23.99	22.2	1.90	2.89

Significance

The method has been taken up by many researchers and chemists who are interested in the use of graphite oxide for other purposes, because it is the fastest[4] conventional method of producing graphite oxide while maintaining a relatively high C/O ratio. When researchers and chemists are introducing a large quantity of graphite oxide within time limitations, Hummers' method is usually referenced in some form.

Modern variations

Graphite oxide captured the attention of the scientific community after the discovery of graphene in 2004. Many teams are looking into ways of using graphite oxide as a shortcut to mass production of graphene. So far, the materials produced by these methods have shown to have more defects than those produced directly from graphite. Hummers' method remains a key point of interest because it is an easy method of producing large quantities of graphite oxide.

Other groups have been focused on making improvements to the Hummers' method to make it more efficient and environmentally friendly. One such process is eliminating the use of NaNO₃ from the process.^[5][6] The addition of persufate (S₂O₈²⁻) ensures the complete oxidation and exfoliation of graphite to yield suspensions of individual graphite oxide sheets. The elimination of nitrate is also advantageous as it stops the production of gases such as nitrogen dioxide and dinitrogen tetraoxide.

Future uses

Besides graphene, Hummers' method has become a point of interest in

After discovering that graphite oxide is reactive to many of the wavelengths of light found within sunlight, teams have been looking into methods of using it to bolster the speed of reaction in decomposition of water and organic matter. The most common method for producing the graphite oxide in these experiments has been Hummers' method.

See also

• Graphite Oxide

References