Iodosilane
| |||
Identifiers | |||
---|---|---|---|
3D model (
JSmol ) |
|||
ChemSpider | |||
PubChem CID
|
|||
CompTox Dashboard (EPA)
|
|||
| |||
| |||
Properties | |||
SiH3I | |||
Molar mass | 158.014 g/mol | ||
Appearance | colorless crystals[1] | ||
Density | 2.070 g·cm−3 (0.5 °C) 2.035 g·cm−3 (14.8 °C)[2] | ||
Melting point | −56.6 °C (216.6 K)[3] | ||
Boiling point | 45.8 °C (318.9 K)[3] | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|
Iodosilane is a
monoclinic crystal of space group P21/c at −157 °C.[1]
Preparation
Iodosilane is the first product of the reaction between
monosilane and iodine, the other products being di-, tri- and finally tetraiodosilane (silicon tetraiodide
).
It can also be produced by the reaction of phenylsilane or chlorophenylsilane with hydrogen iodide.[4]
Properties
At low temperatures, iodosilant quickly reacts with [Co(CO)4]− to form SiH3Co(CO)4.[5]
Further reading
- Nakagawa, Jun; Hayashi, Michiro (1982). "Microwave spectra in the ν3, 2ν3, and ν6 excited states of iodosilane". Journal of Molecular Spectroscopy. 93 (2): 441–444. .
- Ward, Laird G. L.; Norman, Arlan D.; Gondal, S. K.; MacDiarmid, A. G. (1968). "Bromosilane, iodosilane, and trisilylamine". In Jolly, William L.; et al. (eds.). Inorganic Syntheses. Vol. 11. McGraw-Hill. pp. 159–170. ISBN 978-0-470-13170-1.
- Sharbaugh, A. H.; Heath, G. A.; Thomas, L. F.; Sheridan, J. (1953). "Microwave spectrum and structure of iodosilane". Nature. 171 (4341): 87. S2CID 4178870.
References
- ^ doi:10.1107/S0108270188001155. Archived from the original on 2018-06-02. Retrieved 2019-02-25.)
{{cite journal}}
: CS1 maint: multiple names: authors list (link - ISSN 0368-1769. Retrieved 2019-02-25.)
{{cite journal}}
: CS1 maint: multiple names: authors list (link - ^ S2CID 4118995. Archived from the original on 2021-09-14. Retrieved 2019-02-25.)
{{cite journal}}
: CS1 maint: multiple names: authors list (link - OCLC 310719485.
- ISSN 0009-241X.