Thulium acetylacetonate: Difference between revisions

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'''Thulium acetylacetonate''' is a [[coordination compound]] with the formula Tm(C<sub>5</sub>H<sub>7</sub>O<sub>2</sub>)<sub>3</sub>. This anhydrous [[acetylacetonate complex]] is often discussed but unlikely to exist per se. The 8-coordinated dihydrate Tm(C<sub>5</sub>H<sub>7</sub>O<sub>2</sub>)<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub> is a more plausible formula based on the behavior of other lanthanide acetylacetonates. The dihydrate has been characterized by [[X-ray crystallography]].<ref>{{cite journal|journal=Gaodeng Xuexiao Huaxue Xuebao (Chem.J.Chin.Univ.) |year=1983|page=769|volume=4|first1=Shen |last1=Cheng|first2=Fan |last2 =Yuguo|first3=Wang |last3=Yutian|first5=Liu|last5=Guofa|first4=Lu|last4=Pinzhe }}</ref><ref>Cambridge Crystallographic Data Center, number CCDC 1121251.</ref> Upon attempted dehydration by heating under vacuum, other hydrated lanthanide tris(acetylacetonate) complexes decompose to give oxo-clusters.<ref>{{cite journal| first1=Sem Raj | last1=Tamang| first2=Arpita| last2= Singh| first3=Deepika| last3= Bedi| first4=Adineh Rezaei| last4=Bazkiaei| first5=Audrey A.| last5=Warner| first6=Keeley | last6=Glogau| first7=Corey | last7=McDonald| first8=Daniel K. | last8=Unruh| first9=Michael| last9=Findlater|title=Polynuclear Lanthanide–Diketonato Clusters for the Catalytic Hydroboration of Carboxamides and Esters|journal=Nat. Catal.|volume= 3|pages= 154–162|year=2020| issue=2|doi=10.1038/s41929-019-0405-5| s2cid=209897045}}</ref>


'''Thulium acetylacetonate''' is a [[coordination complex]] with the [[chemical formula]] Tm(C<sub>5</sub>H<sub>7</sub>O<sub>2</sub>)<sub>3</sub>, or Tm(acac)<sub>3</sub> for short. It can be prepared by the reaction of [[thulium hydroxide]] and [[ethanol]] solution of [[acetylacetone]].<ref>{{cite book | last=Spencer | first=J.F. | title=The Metals of the Rare Earths | publisher=Longmans, Green | series=Monographs on inorganic and physical chemistry | year=1919 | url=https://books.google.com/books?id=4xBDAAAAIAAJ&pg=PA153 | access-date=2021-09-16 | page=153 | archive-date=2021-09-16 | archive-url=https://web.archive.org/web/20210916173433/https://books.google.com/books?id=4xBDAAAAIAAJ&pg=PA153 }}</ref> Its monohydrate is not volatile in vacuum.<ref>{{cite book | last=Friend | first=J.N. | title=A Text-book of Inorganic Chemistry | publisher=Griffin | issue=v. 4 | year=1917 | url=https://books.google.com/books?id=CwxDAAAAIAAJ&pg=PA438 | access-date=2021-09-16 | page=438 | archive-date=2021-09-16 | archive-url=https://web.archive.org/web/20210916173434/https://books.google.com/books?id=CwxDAAAAIAAJ&pg=PA438 }}</ref> The [[acetonitrile]] solution of its dihydrate and the [[dichloromethane]] solution of 5-[(4-fluorobenzylidene)amino]-8-hydroxyquinoline (HL) react by heating to obtain the complex [Tm<sub>4</sub>(acac)<sub>6</sub>(L)<sub>6</sub>(μ<sub>3</sub>-OH)<sub>2</sub>].<ref>{{cite journal|journal=Dalton Transactions|volume=45|issue=1|language=en|issn=1477-9226|date=2016|pages=253–264|doi=10.1039/C5DT03790E|url=http://xlink.rsc.org/?DOI=C5DT03790E|title=Multiple magnetic relaxation processes, magnetocaloric effect and fluorescence properties of rhombus-shaped tetranuclear rare earth complexes|accessdate=2021-09-20|author1=Hong-Ling Gao |author2=Li Jiang |author3=Shuang Liu |author4=Hai-Yun Shen |author5=Wen-Min Wang |author6=Jian-Zhong Cui|pmid=26600114 }}</ref >
Thulium acetylacetonate can be prepared by the reaction of [[thulium hydroxide]] and [[acetylacetone]].<ref>{{cite book | last=Spencer | first=J.F. | title=The Metals of the Rare Earths | publisher=Longmans, Green | series=Monographs on inorganic and physical chemistry | year=1919 | url=https://books.google.com/books?id=4xBDAAAAIAAJ&pg=PA153 | access-date=2021-09-16 | page=153 | archive-date=2021-09-16 | archive-url=https://web.archive.org/web/20210916173433/https://books.google.com/books?id=4xBDAAAAIAAJ&pg=PA153 }}</ref> Its monohydrate is not volatile.<ref>{{cite book | last=Friend | first=J.N. | title=A Text-book of Inorganic Chemistry | publisher=Griffin | issue=v. 4 | year=1917 | url=https://books.google.com/books?id=CwxDAAAAIAAJ&pg=PA438 | access-date=2021-09-16 | page=438 | archive-date=2021-09-16 | archive-url=https://web.archive.org/web/20210916173434/https://books.google.com/books?id=CwxDAAAAIAAJ&pg=PA438 }}</ref> The [[acetonitrile]] solution of its dihydrate and the [[dichloromethane]] solution of 5-[(4-fluorobenzylidene)amino]-8-hydroxyquinoline (HL) react by heating to obtain the complex [Tm<sub>4</sub>(acac)<sub>6</sub>(L)<sub>6</sub>(μ<sub>3</sub>-OH)<sub>2</sub>].<ref>{{cite journal|journal=Dalton Transactions|volume=45|issue=1|language=en|issn=1477-9226|date=2016|pages=253–264|doi=10.1039/C5DT03790E|url=http://xlink.rsc.org/?DOI=C5DT03790E|title=Multiple magnetic relaxation processes, magnetocaloric effect and fluorescence properties of rhombus-shaped tetranuclear rare earth complexes|accessdate=2021-09-20|author1=Hong-Ling Gao |author2=Li Jiang |author3=Shuang Liu |author4=Hai-Yun Shen |author5=Wen-Min Wang |author6=Jian-Zhong Cui|pmid=26600114 }}</ref >


== References ==
== References ==

Revision as of 19:41, 5 February 2024

Thulium acetylacetonate
Names
Other names
Thulium(III) acetylacetonate
Identifiers
3D model (
JSmol
)
ChemSpider
  • InChI=1S/3C5H8O2.Tm/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3
    Key: ASFMKHGVRGERPB-UHFFFAOYSA-K
  • trihydrate: InChI=1S/3C5H8O2.3H2O.Tm/c3*1-4(6)3-5(2)7;;;;/h3*3,6H,1-2H3;3*1H2;/q;;;;;;+3/p-3/b3*4-3-;;;;
    Key: UZKSYWPAPWYRSV-VBBOVLQFSA-K
  • CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].[Tm+3]
  • trihydrate: CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].[Tm+3].O.O.O
Properties
C15H21O6Tm
Molar mass 466.261 g·mol−1
Appearance powder[1]
white powder (trihydrate)[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Thulium acetylacetonate is a

acetylacetonate complex is often discussed but unlikely to exist per se. The 8-coordinated dihydrate Tm(C5H7O2)3(H2O)2 is a more plausible formula based on the behavior of other lanthanide acetylacetonates. The dihydrate has been characterized by X-ray crystallography.[3][4] Upon attempted dehydration by heating under vacuum, other hydrated lanthanide tris(acetylacetonate) complexes decompose to give oxo-clusters.[5]

Thulium acetylacetonate can be prepared by the reaction of

thulium hydroxide and acetylacetone.[6] Its monohydrate is not volatile.[7] The acetonitrile solution of its dihydrate and the dichloromethane solution of 5-[(4-fluorobenzylidene)amino]-8-hydroxyquinoline (HL) react by heating to obtain the complex [Tm4(acac)6(L)6(μ3-OH)2].[8]

References

  1. ISBN 978-0-8155-1743-6. Archived from the original
    on 2021-10-17. Retrieved 2021-09-16.
  2. ISBN 978-1-4398-1462-8. Archived from the original
    on 2021-09-16. Retrieved 2021-09-16.
  3. ^ Cheng, Shen; Yuguo, Fan; Yutian, Wang; Pinzhe, Lu; Guofa, Liu (1983). Gaodeng Xuexiao Huaxue Xuebao (Chem.J.Chin.Univ.). 4: 769. {{cite journal}}: Missing or empty |title= (help)
  4. ^ Cambridge Crystallographic Data Center, number CCDC 1121251.
  5. S2CID 209897045
    .
  6. ^ Spencer, J.F. (1919). The Metals of the Rare Earths. Monographs on inorganic and physical chemistry. Longmans, Green. p. 153. Archived from the original on 2021-09-16. Retrieved 2021-09-16.
  7. ^ Friend, J.N. (1917). A Text-book of Inorganic Chemistry. Griffin. p. 438. Archived from the original on 2021-09-16. Retrieved 2021-09-16.
  8. PMID 26600114
    . Retrieved 2021-09-20.

External reading
Retrieved from "https://en.wikipedia.org/w/index.php?title=Thulium_acetylacetonate&oldid=1203859569"