1,1'-Ferrocenedicarboxylic acid

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1,1'-Ferrocenedicarboxylic acid
Names
IUPAC name
1,1'-Ferrocenedicarboxylic acid
Identifiers
3D model (
JSmol
)
ChemSpider
ECHA InfoCard
 100.013.699 Edit this at Wikidata
EC Number
  • 215-068-9
  • InChI=1S/2C6H5O2.Fe/c2*7-6(8)5-3-1-2-4-5;/h2*1-4H,(H,7,8);
    Key: ISVVAJYTLASNEJ-UHFFFAOYSA-N
  • [CH]1[CH][CH][C]([CH]1)C(=O)O.[CH]1[CH][CH][C]([CH]1)C(=O)O.[Fe]
Properties
C12H10FeO4
Molar mass 274.053 g·mol−1
Appearance yellow solid
Density 1.769 g/cm3[1]
Hazards
GHS labelling:[2]
GHS07: Exclamation mark
Warning
H315, H319, H335
Related compounds
Related compounds
 Ferrocenecarboxylic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

1,1'-Ferrocenedicarboxylic acid is the

organoiron compound with the formula Fe(C5H4CO2H)2. It is the simplest dicarboxylic acid derivative of ferrocene
. It is a yellow solid that is soluble in aqueous base. The 1,1' part of its name refers to the location of the carboxylic acid groups on separate rings.

It can be prepared by hydrolysis of its diesters Fe(C5H4CO2R)2 (R = Me, Et), which in turn are obtained by treatment of

diisocyanate, the diamide, and diamine, respectively, Fe(C5H4COCl)2, Fe(C5H4NCO)2, Fe(C5H4CONH2)2, and Fe(C5H4NH2)2.[3]

Derivatives of ferrocenedicarboxylic acid are components of some redox switches and redox active coatings.[4][5]

Related compounds

References

  1. hdl:1808/17822
    .
  2. ^ "C&L Inventory". echa.europa.eu. Retrieved 14 October 2022.
  3. doi:10.1021/om4004972
    .
  4. doi:10.1021/la011101t
    .
  5. ISBN 9780841239296
    .
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