2,2'-Biphenylene phosphorochloridite

Add links
Source: Wikipedia, the free encyclopedia.
2,2′-Biphenylene phosphorochloridite
Names
Preferred IUPAC name
6-Chloro-6H-dibenzo[d,f][1,3,2]dioxaphosphepine
Other names
1,1′-Biphenyl-2,2′-diyl phosphorochloridite
Identifiers
3D model (
JSmol
)
ChemSpider
EC Number
  • 929-115-2
  • InChI=1S/C12H8ClO2P/c13-16-14-11-7-3-1-5-9(11)10-6-2-4-8-12(10)15-16/h1-8H
    Key: RKNWJMHQLOIGIH-UHFFFAOYSA-N
  • C1=CC=C2C(=C1)C3=CC=CC=C3OP(O2)Cl
Properties
C12H8ClO0P
Molar mass 218.62 g·mol−1
Appearance white solid
Melting point 63 °C (145 °F; 336 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

2,2′-Biphenylene phosphorochloridite is the name for a polycyclic

phosphite ligands such as BiPhePhos by reaction with suitable diols. 2,2′-Biphenylene phosphorochloridites, which is a white solid, is prepared from 2,2′-biphenol and phosphorus trichloride. It is prepared by the reaction of 2,2′-biphenol and phosphorus trichloride.[1][2]

References

  1. doi:10.1021/ja00058a079
    .
  2. doi:10.1021/OM950549K
    .
Retrieved from "https://en.wikipedia.org/w/index.php?title=2,2%27-Biphenylene_phosphorochloridite&oldid=1195112737"