Bismabenzene

Source: Wikipedia, the free encyclopedia.
Bismabenzene
Names
Preferred IUPAC name
Bismine
Other names
Bismin
Identifiers
3D model (
JSmol
)
ChemSpider
  • InChI=1S/C5H5Bi/c1-2-4-6-5-3-1/h1-5H
    Key: ZEBPXYQZSWNMLH-UHFFFAOYSA-N
  • C1=CC=[Bi]C=C1
Properties
C5H5Bi
Molar mass 274.075 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Bismabenzene (C5H5Bi) is the parent representative of a group of

Diels-Alder addition.[1][2][3]

stibabenzene, and bismabenzene[clarification needed
]

An unstable derivative with 4-alkyl substituents was reported in 1982.

DBU in 2016.[1][5]

References

  1. ^ a b Fernando Gomollon-Bel (September 29, 2016). "Chemists create stable bismuth benzene derivative". Chemistry World.
  2. doi:10.1021/ja00776a063
    .
  3. doi:10.1021/ar50124a005
    . Bismabenzene is so reactive that is exists in the form of a Diels-Alder dimer (10f) at low temperature (<-10 °C).
  4. doi:10.1021/ja00385a024
    .
  5. PMID 27654463
    .
Retrieved from "https://en.wikipedia.org/w/index.php?title=Bismabenzene&oldid=1186240495"