Electron donor

Source: Wikipedia, the free encyclopedia.

In

Lewis base.[1]

In contrast to traditional reducing agents, electron transfer from a donor to an

ionization potential, which is the energy required to remove an electron from the highest occupied molecular orbital (HOMO
).

The overall energy balance (ΔE), i.e., energy gained or lost, in an electron donor-acceptor transfer is determined by the difference between the acceptor's electron affinity (A) and the ionization potential (I):

Molecular electronics and devices

Edge-on view of portion of crystal structure of hexamethyleneTTF/TCNQ charge transfer salt, highlighting the segregated stacking.[2] HexamethyleneTTF, featuring tetrathiafulvalene, is an iconic electron donor in this electron donor-acceptor material.

Electron donors are components of many devices such as

organic photovoltaic devices. Typical electron donors undergo reversible redox so that they can serve as electron relays. Triarylamines are typical donors.[3]

In biology

NADH is an example of a natural electron donor.[4] Ascorbic acid is another example. It is an water-soluble antioxidant.[5]

In

chlorinated solvents like vinyl chloride, soil organic matter, and reduced inorganic compounds are all compounds that can act as electron donors. These reactions are of interest not only because they allow organisms to obtain energy, but also because they are involved in the natural biodegradation
of organic contaminants. When clean-up professionals use monitored natural attenuation to clean up contaminated sites, biodegradation is one of the major contributing processes.


See also

References