Methyl 4-iodobenzoate
Names | |
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Preferred IUPAC name
Methyl 4-iodobenzoate | |
Other names
Methyl p-iodobenzoate
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Identifiers | |
3D model (
JSmol ) |
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ChemSpider | |
ECHA InfoCard
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100.009.635 |
EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
C8H7IO2 | |
Molar mass | 262.046 g·mol−1 |
Appearance | white solid |
Melting point | 114 °C (237 °F; 387 K)[1] |
Hazards | |
GHS labelling:[2] | |
Warning | |
H315, H319, H335, H411 | |
P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Methyl 4-iodobenzoate, or methyl p-iodobenzoate, is an
iodinated derivative of methyl benzoate
.
Preparation
Methyl 4-iodobenzoate may be prepared by the
Reactions
The aryl-iodide functionality of methyl 4-iodobenzoate may undergo coupling reactions, such as a symmetrical Sonogashira coupling with trimethylsilylacetylene (with the TMSA deprotected to acetylene in situ) to form dimethyl 4,4'-(ethyne-1,2-diyl)dibenzoate.[4][5]
References
- ^ "Methyl 4-iodobenzoate". ChemSpider. Retrieved 24 October 2023.
- ^ "Methyl 4-iodobenzoate". pubchem.ncbi.nlm.nih.gov.
- ^ PubChem. "Methyl 4-iodobenzoate". PubChem. Retrieved 24 October 2023.
- ^ PMID 18665295.
- PMID 12227748.