Tris(dibenzylideneacetone)dipalladium(0)
Names | |
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IUPAC name
Tris(dibenzylideneacetone)dipalladium
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Other names
Pd2(dba)3
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Identifiers | |
ECHA InfoCard
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100.122.794 |
PubChem CID
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Properties | |
C51H42O3Pd2 | |
Molar mass | 915.73 g·mol−1 |
Melting point | 152 to 155 °C (306 to 311 °F; 425 to 428 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tris(dibenzylideneacetone)dipalladium(0) or [Pd2(dba)3] is an
homogeneous catalyst in organic synthesis.[1]
Preparation and structure
First reported in 1970,[2] it is prepared from dibenzylideneacetone and sodium tetrachloropalladate. Because it is commonly recrystallized from chloroform, the complex is often supplied as the adduct [Pd2(dba)3·CHCl3].[1] The purity of samples can be variable.[3]
In [Pd2(dba)3], the pair of Pd atoms are separated by 320
pm but are tied together by dba units.[4] The Pd(0) centres are bound to the alkene parts of the dba ligands
.
Applications
[Pd2(dba)3] is used as a source of soluble Pd(0), in particular as a
Trost asymmetric allylic alkylation, as well as Buchwald–Hartwig amination.[5]
Related Pd(0) complexes are [Pd(dba)2][6] and tetrakis(triphenylphosphine)palladium(0).
References
- ^
- .
- .
- ISBN 978-1-891389-53-5.
- ^ John R. Stille, F. Christopher Pigge, Christopher S. Regens, Ke Chen, Adrian Ortiz and Martin D. Eastgate "Bis(dibenzylideneacetone)palladium(0)" E-eros. 2013.