X-ray notation

X-ray notation is a method of labeling

.

Conversion

Conversion^[2][3]

Quantum numbers				Atomic notation	X-ray notation
${\displaystyle n}$	${\displaystyle \ell }$	${\displaystyle s}$	${\displaystyle j}$
1	0	1/2	1/2	1s1/2	K1
2	0	1/2	1/2	2s1/2	L1
2	1	1/2	1/2	2p1/2	L2
2	1	1/2	3/2	2p3/2	L3
3	0	1/2	1/2	3s1/2	M1
3	1	1/2	1/2	3p1/2	M2
3	1	1/2	3/2	3p3/2	M3
3	2	1/2	3/2	3d3/2	M4
3	2	1/2	5/2	3d5/2	M5
4	0	1/2	1/2	4s1/2	N1
4	1	1/2	1/2	4p1/2	N2
4	1	1/2	3/2	4p3/2	N3
4	2	1/2	3/2	4d3/2	N4
4	2	1/2	5/2	4d5/2	N5
4	3	1/2	5/2	4f5/2	N6
4	3	1/2	7/2	4f7/2	N7

Uses

• X-ray sources are classified by the type of material and orbital used to generate them. For example, Cu_Kα X-rays are emitted from the K orbital of copper.
• X-ray absorption is reported as which orbital absorbed the x-ray photon. In EXAFS and XMCD the L-edge or the L absorption edge is the point where the L orbital begins to absorb x-rays.
• Auger peaks are identified with three orbital definitions, for example KL₁L₂. In this case, K represents the hole that is initially present at the core level, L₁ the initial state of the electron that relaxes down into the core level hole, and L₂ the initial energy state of the emitted electron.

See also

• Siegbahn notation for the names of spectral lines used in X-ray spectroscopy
• Spectroscopic notation
• Term symbol notation

References