1,3-Dioxane
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| Names | |
|---|---|
| Preferred IUPAC name
1,3-Dioxane | |
| Other names
Formaldehyde trimethylene acetal
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| Identifiers | |
3D model (
JSmol ) |
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| 102532 | |
| ChEBI | |
| ChemSpider | |
ECHA InfoCard
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100.007.278 |
| EC Number |
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PubChem CID
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RTECS number
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| UNII | |
| UN number | 1165 |
CompTox Dashboard (EPA)
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| Properties | |
| C4H8O2 | |
| Molar mass | 88.106 g·mol−1 |
| Appearance | colorless liquid |
| Melting point | −42 °C (−44 °F; 231 K) |
| Boiling point | 103 °C (217 °F; 376 K) |
| Hazards | |
| GHS labelling: | |
 
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| Danger | |
| H225, H302, H312, H315, H332 | |
| P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P312, P302+P352, P303+P361+P353, P304+P312, P304+P340, P312, P321, P322, P330, P332+P313, P362, P363, P370+P378, P403+P235, P501 | |
| Flash point | 2 °C (36 °F; 275 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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1,3-Dioxane or m-dioxane is an
heterocycle with two oxygen atoms in place of carbon atoms at the 1- and 3- positions. 1,4-Dioxane, which is of greater commercial value, is an isomer. Both dioxanes are colorless liquids.[1]
Preparation and derivatives
The parent 1,3-dioxane is prepared by the reaction of
1,3-propanediol
in the presence of Brönsted or Lewis acid catalysts.
Substituted derivatives can be used as
carbonyl compounds. are prepared from the reaction between a ketone or an aldehyde with 1,3-diols. [2] They can also be produced by the Prins reaction.[3]
Related compounds
1,3-Dioxolanes are five-membered rings with the formula (CH2)3O2.
See also
References
- ISBN 3527306730.
- ISBN 9780471160199. Archivedfrom the original on December 7, 2016. Retrieved June 12, 2020.
- .
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