Counterion

Source: Wikipedia, the free encyclopedia.
cation-exchange resin
, is typically supplied with Na+ as the counterion.

In

table salt (NaCl, also known as sodium chloride) the sodium ion (positively charged) is the counterion for the chloride
ion (negatively charged) and vice versa.

A counterion will be more commonly referred to as an

cation
, depending on whether it is negatively or positively charged. Thus, the counterion to an anion will be a cation, and vice versa.

In

malate is often accumulated in the vacuole to decrease water potential and drive cell expansion. To maintain neutrality, K+ ions are often accumulated as the counterion. Ion permeation through hydrophobic cell walls is mediated by ion transport channels. Nucleic acids are anionic, the corresponding cations are often protonated polyamines
.

Interfacial chemistry

Counterions are the mobile ions in ion exchange polymers and colloids.[1] Ion-exchange resins are polymers with a net negative or positive charge. Cation-exchange resins consist of an anionic polymer with countercations, typically Na+ (sodium). The resin has a higher affinity for highly charged countercations, for example by Ca2+ (calcium) in the case of water softening. Correspondingly, anion-exchange resins are typically provided in the form of chloride Cl−, which is a highly mobile counteranion.

Counterions are used in

phase-transfer catalysis. In a typical application lipophilic countercation such as benzalkonium
solubilizes reagents in organic solvents.

Solution chemistry

Solubility of salts in organic solvents is a function of both the cation and the anion. The solubility of cations in organic solvents can be enhanced when the anion is lipophilic. Similarly, the solubility of anions in organic solvents is enhanced with lipophilic cations. The most common lipophilic cations are quaternary ammonium cations, called "quat salts".

  • Lipophilic counteranions
  • Lithium tetrakis(pentafluorophenyl)borate is the lithium salt of a highly lipophilic tetraarylborate anion, often referred to as a weakly coordinating anion.[2]
    weakly coordinating anion.[2]
  • Tetraphenylborate is less lipophilic than the perfluorinated derivative, but widely used as a precipitating agent.
    Tetraphenylborate is less lipophilic than the perfluorinated derivative, but widely used as a precipitating agent.
  • Hexafluorophosphate is a common weakly coordinating anion.
    weakly coordinating anion
    .
  • As illustrated by the small counteranion tetrafluoroborate (BF− 4), lipophilic cations tend to be symmetric and singly charged.
    As illustrated by the small counteranion tetrafluoroborate (BF−
    4    ), lipophilic cations tend to be symmetric and singly charged.

Many cationic organometallic complexes are isolated with inert, noncoordinating counterions. Ferrocenium tetrafluoroborate is one such example.

Electrochemistry

In order to achieve high ionic conductivity, electrochemical measurements are conducted in the presence of excess electrolyte. In water the electrolyte is often a simple salt such as

dielectric constant.[3]

Counterion stability

For many applications, the counterion simply provides charge and lipophilicity that allows manipulation of its partner ion. The counterion is expected to be chemically inert. For counteranions, inertness is expressed in terms of low

Lewis basicity
. The counterions are ideally rugged and unreactive. For quaternary ammonium and phosphonium countercations, inertness is related to their resistance of degradation by strong bases and strong nucleophiles.

References

  1. doi:10.1351/goldbook.C01371
  2. PMID 15083452
    .
  3. doi:10.1021/ar1000023
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