Halogen dance rearrangement
The halogen dance rearrangement is an
aryl carbanion. The halogen dance concept can be extended from benzene derivatives to other aromatic systems as well, for instance furan[2] and thiophene[3]
compounds.
The halogen dance rearrangement of iodooxazoles was studied by the Stambuli Group.[4]
References
- doi:10.1039/B607701N.
- ^ J. Fröhlich; C. Hametner. "First halogen dance reactions and their selective prevention on bromofurans". Institute of Organic Chemistry, Technical University of Vienna. Retrieved 8 October 2018.
- ^ "Base catalysed halogen dance reactions". Institute of Organic Chemistry, Technical University of Vienna.
- ^ James P. Stambuli; Nicolas Proust; Mathieu F. Chellat (2011). "Mechanistic Insight into the Halogen Dance Rearrangement of Iodooxazoles". Synthesis. 19: 3083–3088. .
General references
- Participation of oligochlorobenzenes in the base-catalyzed halogen dance Martin H. Mach, Joseph F. Bunnett; J. Org. Chem.; 1980; 45(23); 4660-4666.