Hydridotetrakis(triphenylphosphine)rhodium(I)
Identifiers | |
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3D model (
JSmol ) |
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ChemSpider | |
ECHA InfoCard
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100.153.466 |
EC Number |
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CompTox Dashboard (EPA)
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Properties | |
C72H61P4Rh | |
Molar mass | 1153.12 |
Appearance | yellow solid |
Density | 1.328 g/cm3 |
Melting point | 162–163 °C (324–325 °F; 435–436 K) |
Hazards | |
GHS labelling: | |
Warning | |
H315, H319, H335 | |
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Hydridotetrakis(triphenylphosphine)rhodium(I) is the
homogeneous catalyst for hydrogenation and related reactions.[2]
It is a yellow solid that dissolves in aromatic solvents.
Preparation
In the presence of base, H2, and additional triphenylphosphine, Wilkinson's catalyst (chloridotris(triphenylphosphane)rhodium(I)) converts to HRh(PPh3)4:[3]
- RhCl(PPh3)3 + H2 + KOH + PPh3 → RhH(PPh3)4 + H2O + KCl
References
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