Isobutyryl chloride
Appearance
Names | |
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Preferred IUPAC name
2-Methylpropanoyl chloride | |
Other names
Isobutyroyl chloride
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Identifiers | |
3D model (
JSmol ) |
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ChemSpider | |
ECHA InfoCard
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100.001.086 |
PubChem CID
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UNII | |
CompTox Dashboard (EPA)
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Properties | |
C4H7ClO | |
Molar mass | 106.55 g·mol−1 |
Density | 1.017 g/mL[1] |
Melting point | −90 °C[1] |
Boiling point | 91–93 °C (196–199 °F; 364–366 K)[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Isobutyryl chloride (2-methylpropanoyl chloride) is the organic compound with the formula (CH3)2CHCOCl. A colorless liquid, it the simplest branched-chain acyl chloride. It is prepared by chlorination of isobutyric acid.[2]
Reactions
As an ordinary acid chloride, isobutyryl chloride is the subject of many reported transformations. Dehydrohalogenation of isobutyryl chloride with triethylamine gives
2,2,4,4-tetramethylcyclobutanedione.[3] Treatment of isobutyryl chloride with hydrogen fluoride gives the acid fluoride.[4]