Johannes Wislicenus

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Johannes Wislicenus
University of Leipzig
Doctoral studentsCarl Bosch
William Henry Perkin
Harold Carpenter

Johannes Wislicenus (German pronunciation: [joˈhanəs vɪsliˈt͜seːnʊs]; 24 June 1835 – 5 December 1902) was a German chemist, most famous for his work in early stereochemistry.

Biography

The son of the radical Protestant theologian

University of Leipzig, where he died on 6 December 1902.[2]

Research

By the late 1860s,[

J. H. van't Hoff's theory of the tetrahedral carbon atom, believing that it, together with the supposition that there are "specially directed forces, the affinity-energies",[2] which determine the relative position of atoms in the molecule, afforded a method by which the spatial arrangement of atoms in particular cases may be ascertained by experiment. While at Würzburg, Wislicenus developed the use of ethyl aceto acetate in organic synthesis.[2] However, he was also active in inorganic chemistry, finding a reaction for the production of sodium azide. He was the first to prepare cyclopentane in 1893[4]

Awards

In 1898 Wislicenus was awarded the Davy Medal by the Royal Society of London.[2]

Notes

  1. ^ The New International Encyclopedia. Vol. 23 (2nd ed.). New York: Dodd, Mead and Company. 1916. p. 731.
  2. ^ a b c d e f g h Chisholm 1911.
  3. ^ Chemical Structure, Spatial Arrangement: The Early History of Stereochemistry, 1874–1914. Routledge. 2017.
  4. ^ J. Wislicenus and W. Hentschel (1893) "Der Pentamethenylalkohol und seine Derivate" (Cyclopentanol and its derivatives), Annalen der Chemie, 275 : 322-330; see especially pages 327-330. Wislicenus prepared cyclopentane from cyclopentanone ("Ketopentamethen"), which is prepared by heating calcium adipate.

References

Attribution

Further reading