Kläui ligand
The Kläui ligand is the anion {(C5H5)Co[(CH3O)2PO]3}−. The
tridentate and tripodal anionic ligands include trispyrazolylborates
.
General structure of a metal center coordinated to a κ3-Kläui ligand.
The ligand is derived from the cationic complex of
chelate) complexes of the type {M[{(C5H5)Co[(CH3O)2PO]3}2]n+ (M = Co(II), Mn(II), Bi(III), etc.).[3]
References
- ^ W. Kläui, P. C. Kunz "Sodium (η5-Cyclopentadienyl)tris(dimethylphosphito-P)cobalt(III), Na[(C5H5)Co{P(O)(OMe)2}3]" Inorg. Synth., 2010 vol. 35, pp. 125–128.