Methylenecyclohexane

Source: Wikipedia, the free encyclopedia.
Methylenecyclohexane
Names
Preferred IUPAC name
Methylidenecyclohexane
Other names
Methylenecyclohexane
Identifiers
3D model (
JSmol
)
ChemSpider
ECHA InfoCard
 100.013.412 Edit this at Wikidata
EC Number
  • 214-752-4
UNII
  • InChI=1S/C7H12/c1-7-5-3-2-4-6-7/h1-6H2 checkY
    Key: YULMNMJFAZWLLN-UHFFFAOYSA-N checkY
  • InChI=1/C7H12/c1-7-5-3-2-4-6-7/h1-6H2
    Key: YULMNMJFAZWLLN-UHFFFAOYAJ
  • C=C1CCCCC1
Properties
C7H12
Molar mass 96.170 g/mol
Boiling point 102 to 103 °C (216 to 217 °F; 375 to 376 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Methylenecyclohexane (IUPAC name: methylidenecyclohexane) is an organic compound with the molecular formula C7H12.

Synthesis

It can be produced by a Wittig reaction or a reaction with a Tebbe's reagent from cyclohexanone.[1][2][3] It can also be synthesized as a side product of the dehydration of 2-methylcyclohexanol into 1-methylcyclohexene.

Structure

Methylenecyclohexane is an unsaturated hydrocarbon, containing a cyclohexane ring with a methylene (methylidine) group attached.

See also

References

  1. doi:10.15227/orgsyn.040.0066
    .
  2. ISBN 978-0-470-04610-4
    . I this way, cyclohexanone is transformed into methylenecyclohexene and benzaldehyde into stryene.
  3. ISBN 978-1-118-00538-5
    . Now, when cyclohexanone is added to the solution in which the [Tebbe] reagent has been generated, reaction occurs to produce methylenecyclohexane and triphenylphosphine oxide
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