Network covalent bonding
A network solid or covalent network solid (also called atomic crystalline solids or giant covalent structures)
Examples of network solids include diamond with a continuous network of carbon atoms and silicon dioxide or quartz with a continuous three-dimensional network of SiO2 units. Graphite and the mica group of silicate minerals structurally consist of continuous two-dimensional sheets covalently bonded within the layer, with other bond types holding the layers together.[3] Disordered network solids are termed glasses. These are typically formed on rapid cooling of melts so that little time is left for atomic ordering to occur.[4]
Properties
- Hardness: Very hard, due to the strong covalent bonds throughout the lattice (deformation can be easier, however, in directions that do not require the breaking of any covalent bonds, as with flexing or sliding of sheets in graphite or mica).
- Melting point: High, since melting means breaking covalent bonds (rather than merely overcoming weaker intermolecular forces).[5]
- Solid-phase electrical conductivity: Variable,[6] depending on the nature of the bonding: network solids in which all electrons are used for sigma bonds (e.g. diamond, quartz) are poor conductors, as there are no delocalized electrons. However, network solids with delocalized pi bonds (e.g. graphite) or dopantscan exhibit metal-like conductivity.
- Liquid-phase electrical conductivity: Low, as the macromolecule consists of neutral atoms, meaning that melting does not free up any new charge carriers (as it would for an ionic compound).
- Solubility: Generally insoluble in any solvent due to the difficulty of solvating such a large molecule.
Examples
- Boron nitride (BN)
- Diamond (carbon, C)
- Quartz (SiO2)
- Rhenium diboride (ReB2)
- Silicon carbide (moissanite, carborundum, SiC)
- Silicon (Si)
- Germanium (Ge)
- Aluminium nitride (AlN)
See also
References
- ^ "Properties of solids". www.chem.fsu.edu. Retrieved 2021-02-08.
- ^ "12.7: Types of Crystalline Solids- Molecular, Ionic, and Atomic". Libretexts. 2018-05-20. Retrieved 2021-02-08.
- ^ ISBN 0-618-03591-5
- ^ Zarzycki, J. Glasses and the vitreous state, Cambridge University Press, New York, 1982.
- ^ Ebbing, Darrell D., and R.A.D. Wentworth. Introductory Chemistry. 2nd ed. Boston: Houghton Mifflin, 1998. Print.
- ISBN 978-0-13-600617-6.
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