Ouzo effect

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The ouzo effect during the preparation of absinthe

The ouzo effect (

arak, sambuca and absinthe. Such emulsions occur with only minimal mixing and are highly stable.[1]

Observation and explanation

Arak with water and ice

First a strongly

hydrophobic essential oil such as trans-anethole is dissolved in a water-miscible solvent, such as ethanol, and the ethanol itself forms a solution (a homogenous mixture
) with water.

If then the concentration of ethanol is lowered by addition of more water the hydrophobic substance precipitates from the solution and forms an emulsion with the remaining ethanol-water-mixture. The tiny droplets of the substance in the emulsion scatter light and thus make the mixture appear white.

Oil-in-water

macroscopic levels. Addition of a small amount of surfactant or the application of high shear rates
(strong stirring) can stabilize the oil droplets.

In a water-rich ouzo mixture the droplet coalescence is dramatically slowed without mechanical agitation, dispersing agents, or surfactants. It forms a stable homogeneous fluid

micron.[3]

Using dynamic light scattering, Sitnikova et al.[1] showed that the droplets of oil in the emulsion grow by Ostwald ripening, and that droplets do not coalesce. The Ostwald ripening rate is observed to diminish with increasing ethanol concentrations until the droplets stabilize in size with an average diameter of 3microns.

Based on thermodynamic considerations of the multi-component mixture, the emulsion derives its stability from trapping between the binodal and spinodal curves in the phase diagram.[3] However, the microscopic mechanisms responsible for the observed slowing of Ostwald ripening rates at increasing ethanol concentrations appear not fully understood.

Applications

Video of water being poured into a solution of 151-proof
Everclear and essential oils from grapefruit
rinds.

Emulsions have many commercial uses. A large range of prepared food products, detergents, and body-care products take the form of emulsions that are required to be stable over a long period of time. The ouzo effect is seen as a potential mechanism for generating surfactant-free emulsions without the need for high-shear stabilisation techniques that are costly in large-scale production processes. The creation of a variety of dispersions such as pseudolatexes, silicone emulsions, and biodegradable polymeric nanocapsules, have been synthesized using the ouzo effect, though as stated previously, the exact mechanism of this effect remains unclear.[4] Nanoparticles formed using the ouzo effect are thought to be kinetically stabilized as opposed to thermodynamically stabilized micelles formed using a surfactant due to the fast solidification of the polymer during the preparation process.[5]

See also

References

  1. ^
    PMID 16042427. Archived from the original
    (PDF) on 2009-03-18. Retrieved 2007-01-29.
  2. doi:10.1021/la026842o
    .
  3. ^
    doi:10.1016/S0927-7757(03)00331-5. Archived from the original
    (PDF) on 2006-11-27. Retrieved 2007-01-29.
  4. PMID 15751338
    .
  5. PMID 28943210
    .

External links

Media related to Ouzo effect at Wikimedia Commons

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