Rubidium pertechnetate

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Rubidium pertechnetate
Identifiers
3D model (
JSmol
)
  • InChI=1S/4O.Rb.Tc/q4*-2;+1;+7
    Key: XBKKTBUGAOIDLF-UHFFFAOYSA-N
  • [Rb+].[O-][Tc](=O)(=O)=O
Properties
O4RbTc
Molar mass 247 g·mol−1
Appearance white solid[1]
1.167 g/100mL[1]
Structure
tetragonal
I41/a
a = 576.2 pm, c = 1354.3 pm
Related compounds
Other anions
Rubidium perchlorate
Rubidium permanganate
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Rubidium pertechnetate is a pertechnetate of rubidium, with the chemical formula RbTcO4.

Preparation

Rubidium pertechnetate can be prepared by reacting rubidium carbonate with ammonium pertechnetate:[2]

Rb2CO3 + 2 NH4TcO4 → 2 RbTcO4 + (NH4)2CO3

Properties

Rubidium pertechnetate crystallizes in the

lattice parameters a = 576.2 pm and c = 1354.3 pm. In its structure, the Tc–O bond length is 172.3 pm, O–Tc–O bond angle is 108.34°.[2]

References

  1. ^ .