Triethylsilane

Triethylsilane
Names
	Preferred IUPAC name Triethylsilane
Identifiers
CAS Number	617-86-7 ;
3D model ( JSmol)	Interactive image;
ChemSpider	11555;
ECHA InfoCard	100.009.579
EC Number	210-535-3;
PubChem CID	12052;
UNII	0F9429873L ;
CompTox Dashboard (EPA)	DTXSID20870702 ;
	InChI InChI=1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3 Key: AQRLNPVMDITEJU-UHFFFAOYSA-N;
	SMILES CC[SiH](CC)CC;
Properties
Chemical formula	C6H16Si
Molar mass	116.28 g/mol
Appearance	colorless liquid
Density	0.728 g/mL
Melting point	−156.1 °C (−249.0 °F; 117.0 K)
Boiling point	107–108 °C (225–226 °F; 380–381 K)
log P	3.08
Vapor pressure	31 hPa at 20 °C; 75 hPa at 38 °C; 126 hPa at 50 °C
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H225, H412
Precautionary statements	P210, P273
Flash point	−2.99 °C (26.62 °F; 270.16 K) closed cup
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Triethylsilane is the

organosilicon compound with the formula (C₂H₅)₃SiH. It is a trialkylsilane. The Si-H bond is reactive. This colorless liquid is used in organic synthesis as a reducing agent and as a precursor to silyl ethers.^[2] As one of the simplest trialkylsilanes that is a liquid at room temperature, triethylsilane is often used in studies of hydrosilylation catalysis.^[3]

Additional reading

Richard T. Beresis, Jason S. Solomon, Michael G. Yang, Nareshkumar F. Jain, and James S. Panek (1998). "Synthesis of Chiral (E)-Crotylsilanes: [3R- AND 3S-]-(4E)-Methyl 3-(Dimethylphenylsilyl)-4-Hexenoate ". Organic Syntheses. 75: 78{{cite journal}}: CS1 maint: multiple names: authors list (link).
Alessandro Dondoni and Daniela Perrone (2000). "Diastereoselective Synthesis of Protected Vicinal Amino Alcohols: (S)-2-[(4S)-N-tert-Butoxycarbonyl-2,2-Dimethyl-1,3,-oxazolidinyl]-2-tert-butyldimethylsiloxyethanal from a Serine-Derived Aldehyde ". Organic Syntheses. 77: 78.
Pape C. (1881). "Über Siliziumpropylverbindungen". Ber. 14: 1873.
Charles A. Kraus & Walter K. Nelson (1934). "The Chemistry of the Triethylsilicyl Group". doi:10.1021/ja01316a062
.

References

^ ^a ^b ^c Sigma-Aldrich Co., Triethylsilane. Retrieved on 2015-01-30.

ISBN 978-0471936237
.

doi:10.1021/ja00059a008
.

Retrieved from "https://en.wikipedia.org/w/index.php?title=Triethylsilane&oldid=1096741127"

[sigma-1] Sigma-Aldrich Co., Triethylsilane. Retrieved on 2015-01-30.

[2] ISBN 978-0471936237
.

[3] :10.1021/ja00059a008
.

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