Cobalt-60

Source: Wikipedia, the free encyclopedia.
Cobalt-60, 60Co
gamma-rays)
1.1732,1.3325
Isotopes of cobalt
Complete table of nuclides
γ-ray spectrum of cobalt-60

Cobalt-60 (60Co) is a

MeV
, hence the overall equation of the nuclear reaction (activation and decay) is: 59
27
Co
+ n → 60
27
Co
60
28
Ni
+ e + 2 γ

Activity

Given its half-life, the radioactive activity of a gram of 60Co is close to 42 TBq (1,100 Ci). The absorbed dose constant is related to the decay energy and time. For 60Co it is equal to 0.35 mSv/(GBq h) at one meter from the source. This allows calculation of the equivalent dose, which depends on distance and activity.

For example, 2.8 GBq or 60 μg of 60Co, generates a dose of 1 mSv at 1 meter away, within an hour. The swallowing of 60Co reduces the distance to a few millimeters, and the same dose is achieved within seconds.

Test sources, such as those used for school experiments, have an activity of <100 kBq. Devices for nondestructive material testing use sources with activities of 1 TBq and more.

The high γ-energies correspond to a significant mass difference between 60Ni and 60Co: 0.003 

u. This amounts to nearly 20 watts
per gram, nearly 30 times larger than that of 238Pu.

Decay

The decay scheme of 60Co and 60mCo.

The diagram shows a simplified decay scheme of 60Co and 60mCo. The main β-decay transitions are shown. The probability for population of the middle energy level of 2.1 MeV by β-decay is 0.0022%, with a maximum energy of 665.26 keV. Energy transfers between the three levels generate six different gamma-ray frequencies.[7] In the diagram the two important ones are marked. Internal conversion energies are well below the main energy levels.

60mCo is a nuclear isomer of 60Co with half-life 10.467 minutes.[4] It decays by internal transition to 60Co, emitting 58.6 keV gamma rays, or with a low probability (0.22%) by β-decay into 60Ni.[7]

Applications

Security screening of cars at Super Bowl XLI using 60Co gamma-ray scanner (2007)

The main advantage of 60Co is that it is a high-intensity gamma-ray emitter with a relatively long half-life, 5.27 years, compared to other gamma ray sources of similar intensity. The β-decay energy is low and easily shielded; however, the gamma-ray emission lines have energies around 1.3 MeV, and are highly penetrating. The physical properties of cobalt such as resistance to bulk oxidation and low solubility in water give some advantages in safety in the case of a containment breach over some other gamma sources such as caesium-137. The main uses for 60Co are:

Cobalt has been discussed as a "salting" element to add to nuclear weapons, to produce a cobalt bomb, an extremely "dirty" weapon which would contaminate large areas with 60Co nuclear fallout, rendering them uninhabitable. In one design, the tamper of the weapon would be made of 59Co. When the bomb explodes, neutrons from the nuclear fission would irradiate the cobalt and transmute it to 60Co. No country is known to have done any serious development of this type of weapon.

teletherapy machine for cancer radiotherapy, early 1950s.
Brookhaven plant mutation experiment using 60Co source in the pipe, center.

Production

60Co does not occur naturally on Earth in significant amounts; so 60Co is synthesized by bombarding a 59Co target with a

59Co + n → 60Co

Safety

After entering a living mammal (such as a human), some of the 60Co is excreted in feces. The rest is taken up by tissues, mainly the liver, kidneys, and bones, where the prolonged exposure to gamma radiation can cause cancer. Over time, the absorbed cobalt is eliminated in urine.[9]

Steel contamination

Cobalt is found in steel. Uncontrolled disposal of 60Co in scrap metal is responsible for the radioactivity in some iron products.[14][15]

Circa 1983, construction was finished of 1700 apartments in Taiwan which were built with steel contaminated with cobalt-60. About 10,000 people occupied these buildings during a 9–20 year period. On average, these people unknowingly received a radiation dose of 0.4 Sv. This large group did not suffer a higher incidence of cancer mortality, as the linear no-threshold model would predict, but suffered a lower cancer mortality than the general Taiwan public.[dubious ] These observations appear to be compatible with the radiation hormesis model.[16]

In August 2012,

US Customs and Border Protection determined that they were emitting low levels of radiation, which was determined to be from 60Co that had contaminated the steel.[17]

In May 2013, a batch of metal-studded belts sold by online retailer

ASOS were confiscated and held in a US radioactive storage facility after testing positive for 60Co.[18]

Incidents involving medical radiation sources

A radioactive contamination incident occurred in 1984 in Ciudad Juárez, Mexico, originating from a radiation therapy unit illegally purchased by a private medical company and subsequently dismantled for lack of personnel to operate it. The radioactive material, 60Co, ended up in a junkyard, where it was sold to foundries that inadvertently smelted it with other metals and produced about 6,000 tons of contaminated rebar.[19] These were distributed in 17 Mexican states and several cities in the United States. It is estimated that 4,000 people were exposed to radiation as a result of this incident.[19]

In the Samut Prakan radiation accident in 2000, a disused radiotherapy head containing a 60Co source was stored at an unsecured location in Bangkok, Thailand and then accidentally sold to scrap collectors. Unaware of the danger, a junkyard employee dismantled the head and extracted the source, which remained unprotected for a period of days at the junkyard. Ten people, including the scrap collectors and workers at the junkyard, were exposed to high levels of radiation and became ill. Three junkyard workers later died of their exposure, which was estimated to be over 6 Gy. Afterward, the source was safely recovered by Thai authorities.[20]

In December 2013, a truck carrying a disused 111 TBq 60Co

radiation sickness was mild enough that the suspects were quickly released to police custody,[25] and no one is known to have died from the incident.[26]

Other incidents

On 13 September 1999, six people tried to steal 60Co rods from a chemical plant in the city of Grozny, Chechen Republic.[27] During the theft, the suspects opened the radioactive material container and handled it, resulting in the deaths of three of the suspects and injury of the remaining three. The suspect who held the material directly in his hands died of radiation exposure 30 minutes later. This incident is described as an attempted theft, but some of the rods are reportedly still missing.[28]

Parity

In 1957,

violates parity conservation
.

Suppliers

Argentina, Canada, India and Russia are the largest suppliers of 60Co in the world.

light water reactors, allowing for a lower speed of neutrons, which increases the neutron cross section
and decreases the rate of unwanted (n,2n) "knockout" reactions.

In popular culture

60Co is the material encasing a missile nuclear warhead in the 1970 film Beneath the Planet of the Apes.

See also

References

  1. ^ "Radionuclide Half-Life Measurements". National Institute of Standards and Technology. Archived from the original on 12 August 2016. Retrieved 7 November 2011.
  2. ^ "Chart of Nucleids". National Nuclear Data Center. Brookhaven National Laboratory. Archived from the original on 22 May 2008. Retrieved 25 October 2018.
  3. .
  4. ^
    PMID 19285593. {{cite book}}: |journal= ignored (help
    )
  5. )
  6. ^ a b "Table of Isotopes decay data". Retrieved April 16, 2012.
  7. ^ a b Gamma Irradiators For Radiation Processing (PDF). IAEA. 2005. Archived from the original (PDF) on 2018-08-27. Retrieved 2012-04-16.
  8. ^ a b c d "Cobalt | Radiation Protection | US EPA". EPA. Archived from the original on April 13, 2015. Retrieved April 16, 2012.
  9. ^ "Nuclear "birth control" helps Croatia fruit farmers fight flies". Reuters. October 2, 2012 – via www.reuters.com.
  10. ^ "Isotope Production: Dual Use Power Plants - Atomic Insights". atomicinsights.com. June 1, 1996.
  11. ^ NJ.com, Bill Gallo Jr | For (November 12, 2010). "PSEG Nuclear's Hope Creek reactor back on line, begins production of Cobalt-60". nj.{{cite web}}: CS1 maint: multiple names: authors list (link) CS1 maint: numeric names: authors list (link)
  12. ^ "A Nuclear Power Side Venture: Medical Isotope Production". May 2020.
  13. ^ "Information Notice No. 83-16: Contamination of the Auburn Steel Company Property with Cobalt-60". NRC Web.
  14. ^ "Lessons Learned The Hard Way". IAEA Bulletin 47-2. International Atomic Energy Agency. Archived from the original on 18 July 2010. Retrieved 16 April 2010.
  15. PMID 18648557
    .
  16. ^ "Petco Recalls Some Stainless Steel Pet Bowls Due to Cobalt-60 Contamination". 10 August 2012. Retrieved 21 August 2012.
  17. ^ "Asos Belts Seized Over Radioactive Studs". Sky News. 2013-05-28. Retrieved 2013-12-05.
  18. ^ from the original on February 8, 2015. Retrieved 2022-02-10.
  19. IAEA
    . 2002. Retrieved 2012-04-14.
  20. ^ "Mexico Informs IAEA of Theft of Dangerous Radioactive Source". IAEA. 4 December 2013. Retrieved 2013-12-05.
  21. ^ a b "Mexico Says Stolen Radioactive Source Found in Field". IAEA. 2013-12-05. Retrieved 2013-12-05.
  22. ^ Will Grant (2013-12-05). "BBC News - Mexico radioactive material found, thieves' lives 'in danger'". BBC. Retrieved 2013-12-05.
  23. ^ Gabriela Martinez, and Joshua Partlow (6 December 2013). "Thieves who stole lethal radioactive cobalt-60 in Mexico likely doomed". Los Angeles Daily News. Retrieved 12 March 2015.
  24. ^ M. Alex Johnson (6 December 2013). "Six released from Mexican hospital but detained in theft of cobalt-60". NBC News. Retrieved 12 March 2015.
  25. ^ Mary Cuddehe (13 November 2014). "What Happens When A Truck Carrying Radioactive Material Gets Robbed In Mexico". BuzzFeed. Retrieved 12 March 2015.
  26. ^ Wm. Robert Johnston (8 April 2005). "Gronzy orphaned source, 1999". Retrieved 16 March 2024.
  27. ^ "Criminal Dies Stealing Radioactive Material". James Martin Center for Nonproliferation Studies at the Monterey Institute of International Studies. 14 September 1999. Archived from the original on 6 October 2021. Retrieved 6 October 2021.{{cite web}}: CS1 maint: bot: original URL status unknown (link)
  28. .
  29. ^ "The Canadian Ghost Town That Tesla Is Bringing Back to Life". Bloomberg.com. 2017-10-31. Retrieved 2018-05-22.
  30. ^ "Nuclear Power in India | Indian Nuclear Energy - World Nuclear Association". world-nuclear.org.
  31. ^ "Bulletin 2022" (PDF). britatom.gov.in. Retrieved 12 May 2023.

External links


Lighter:
cobalt-59
Cobalt-60 is an
isotope of cobalt
Heavier:
cobalt-61
iron-60
Decay chain
of cobalt-60
nickel-60