Opalescence

Source: Wikipedia, the free encyclopedia.
Rough sample of common opal
Rough sample of precious opal, showing iridescence

Opalescence or play of color is the

optical phenomenon displayed by the mineraloid gemstone opal,[1] a hydrated silicon dioxide.[2]

Definition

Each of the three notable types of opal – precious, common, and fire[3] – display different optical effects; therefore, the intended meaning varies depending on context.

  • The general definition of opalescence is a milky iridescence displayed by an opal, which describes the visual effect of precious opal very well, and opalescence is commonly used in lay terms as a synonym for iridescence.[4]
  • In contrast, common opal does not display an iridescence, but often exhibits a hazy sheen of light from within the stone – the phenomenon that gemologists strictly term as opalescence.[5] This milky sheen displayed by opal is a form of adularescence.[6]
  • Fire opal is a relatively transparent gemstone with a vivid yellow-orange-red color and rarely displays iridescence.[2]

Mechanism

The optical effects seen in various types of opal are a result of

silica spheres are relatively small, refracted blue-green colors are prevalent; when relatively larger, refracted yellow-orange-red colors are seen; and when larger yet, reflection yields a milky-hazy sheen.[2][6]

Tyndall effect in opalescent glass: it appears blue from the side, but orange light shines through.[7]

In a physical sense, some cases of opalescence could be related to a type of dichroism seen in highly dispersed systems with little opacity. Due to Rayleigh scattering, a transparent material appears yellowish-red in transmitted white light and blue in the scattered light perpendicular to the transmitted light.[7] The phenomenon illustrated in the bottom photo is an example of the Tyndall effect.

See also

References

  1. ^ opalescent. 2019. In Noah Webster's 1828 American Dictionary of the English Language. Retrieved January 7, 2019, from https://1828.mshaffer.com/d/word/opalescent
  2. ^ a b c d "Opal Gemstone Information". Gemstone Select. 2018. Retrieved 2019-01-08.
  3. ^ a b Douma, M., curator. 2008. Opal. In Cause of Color. Retrieved January 8, 2019, from https://webexhibits.org/causesofcolor/15F.html
  4. ^ "opalescent". Merriam-Webster.com Dictionary. Retrieved 2019-01-08.
  5. ^ "Opal Description". Gemological Institute of America. 2019. Retrieved 2019-01-08.
  6. ^ a b Smigel, Barbara W. 2012. Optical Phenomena in Gemstones. In Introduction to Gemology. Retrieved January 8, 2019, from http://www.bwsmigel.info/Lesson6/DE.Optical.Phenomena.html
  7. ^ a b Douma, M., curator. (2008). Blue and Red. In Cause of Color. Retrieved 2005 from http://www.webexhibits.org/causesofcolor/14B.html