Protonic ceramic fuel cell

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Scheme of a proton conducting fuel cell

A protonic ceramic fuel cell or PCFC is a

which?] of high temperature molten carbonate and solid oxide fuel cells, while exhibiting all of the intrinsic benefits of proton conduction in proton-exchange membrane fuel cells (PEMFC) and phosphoric acid fuel cells (PAFC). PCFCs exhaust water at the cathode and unused fuel, fuel reactant products and fuel impurities at the anode. Common chemical compositions of the ceramic membranes are barium zirconate (BaZrO3),[1] caesium dihydrogen phosphate (CsH2PO4),[6] and complex solid solutions of those materials with other ceramic oxides. The acidic oxide ceramics are sometimes broken into their own class of protonic ceramic fuel cells termed "solid acid fuel cells
".

Some PCFCs operate at high enough temperatures that fuels can be electrochemically oxidized at the anode, not needing the intermediate step of producing hydrogen through reforming process[citation needed]. In this setting, gaseous molecules of the hydrocarbon fuel are absorbed on the surface of the anode in the presence of water vapor, with carbon dioxide as the primary reaction product; hydrogen atoms are efficiently stripped off to be turned into H+ ions then moving into the electrolyte to the other side (cathode) where they react with oxygen in the air to produce water. Other PCFCs operate at lower temperatures and utilize chemical catalysts in addition to electrochemical catalysts to produce hydrogen for the reduction reaction.[4]

Applications and commercial development

PCFCs operating at intermediate temperature of 200 - 400 degrees Celsius have been proposed for heavy duty trucking.[7] Remote power applications using PCFCs have been demonstrated at Canadian oil wells.[8]

See also

References

Further reading