Zirconium perchlorate
Identifiers | |
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3D model (
JSmol ) |
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Properties | |
Cl4O16Zr | |
Molar mass | 489.01 g·mol−1 |
Appearance | white crystals, deliquescent
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Melting point | 96 °C (205 °F; 369 K) |
Boiling point | decomposition |
high | |
Related compounds | |
Other anions
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Zirconium nitrate Zirconyl perchlorate |
Other cations
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Titanium perchlorate Hafnium perchlorate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Zirconium perchlorate is a molecular substance containing
Properties
Zirconium perchlorate is very
In the gas phase the Zr(ClO4)4 molecule has a D4 symmetry with eightfold
In the solid phase, Zr(ClO4)4 crystals are
Related substances
Double salts of zirconium perchlorate are called perchloratozirconates or hexaperchloratozirconates. Known salts include caesium perchloratozirconate (Cs2Zr(ClO4)6), and nitrile perchloratozirconate(sic)[4] ((NO2)2Zr(ClO4)6).[5] Other perchloratozirconates with varying numbers of perchlorate groups also include CsZr(ClO4)5, Cs3Zr(ClO4)7, and Cs4Zr(ClO4)8.[6]
Zirconyl perchlorate (CAS: 15607-09-7) is another perchlorate of zirconium with the formula ZrO(ClO4)2. It is synthesized by reacting Zr(OH)4 with HClO4, then the colorless crystals are formed by slow evaporation.[7]
References
- ^ .
- ^ Lapshina, S.B.; Ermolaeva, L.I.; Girichev, G.V.; Spiridonov, V.P.; Golubinskii, A.V. (1999). "Electron Diffraction Study of the Molecular Structure of Zirconium Perchlorate in the Gas Phase". Russian Journal of Inorganic Chemistry. 44 (4): 485–488.
- ISSN 0132-344X.
- ^ dinitro perchloratozirconate
- S2CID 96641367.
- ^ Babaeva, V.P.; Rosolovski, V.Ya. (1978). "Synthesis and properties of cesium perchloratozirconates". Zhurnal Neorganicheskoj Khimii. 23 (4): 955–959.
- S2CID 34179500.