Amorphous carbon
Amorphous carbon is free, reactive carbon that has no
In mineralogy
This article may need to be rewritten to comply with Wikipedia's quality standards. (December 2012) |
In
. Commercial carbon also usually contains significant quantities of other elements, which may also form crystalline impurities.In modern science
With the development of modern thin film deposition and growth techniques in the latter half of the 20th century, such as
True amorphous carbon has localized π electrons (as opposed to the
The properties of amorphous carbon films vary depending on the parameters used during deposition. The primary method for characterizing amorphous carbon is through the ratio of sp2 to sp3
Experimentally, sp2 to sp3 ratios can be determined by comparing the relative intensities of various spectroscopic peaks (including EELS, XPS, and Raman spectroscopy) to those expected for graphite or diamond. In theoretical works, the sp2 to sp3 ratios are often obtained by counting the number of carbon atoms with three bonded neighbors versus those with four bonded neighbors. (This technique requires deciding on a somewhat arbitrary metric for determining whether neighboring atoms are considered bonded or not, and is therefore merely used as an indication of the relative sp2-sp3 ratio.)
Although the characterization of amorphous carbon materials by the sp2-sp3 ratio may seem to indicate a one-dimensional range of properties between graphite and diamond, this is most definitely not the case. Research is currently ongoing into ways to characterize and expand on the range of properties offered by amorphous carbon materials.
All practical forms of hydrogenated carbon (e.g. smoke, chimney soot, mined coal such as bitumen and anthracite) contain large amounts of polycyclic aromatic hydrocarbon tars, and are therefore almost certainly carcinogenic.
Q-carbon
Q-carbon, short for quenched carbon, is claimed to be a type of amorphous carbon that is ferromagnetic, electrically conductive, harder than diamond,[3] and able to exhibit high-temperature superconductivity.[4] A research group led by Professor Jagdish Narayan and graduate student Anagh Bhaumik at North Carolina State University announced the discovery of Q-carbon in 2015.[5] They have published numerous papers on the synthesis and characterization of Q-carbon,[6] but years later, there is no independent experimental confirmation of this substance and its properties.
According to the researchers, Q-carbon exhibits a random amorphous structure that is a mix of 3-way (sp2) and 4-way (sp3) bonding, rather than the uniform sp3 bonding found in diamonds.[7] Carbon is melted using nanosecond laser pulses, then quenched rapidly to form Q-carbon, or a mixture of Q-carbon and diamond. Q-carbon can be made to take multiple forms, from nanoneedles to large-area diamond films. The researchers also reported the creation of nitrogen-vacancy nanodiamonds[8] and Q-boron nitride (Q-BN), as well as the conversion of carbon into diamond and h-BN into c-BN[9] at ambient temperatures and air pressures.[10] The group obtained patents on q-materials and intended to commercialize them.[11]
In 2018, a team at University of Texas at Austin used simulations to propose theoretical explanations of the reported properties of Q-carbon, including the record high-temperature superconductivity, ferromagnetism and hardness.[12][13] However, their simulations have not been verified by other researchers.
See also
References
- .
- ^
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- ISSN 0362-4331. Retrieved Sep 22, 2019.
- ISSN 0021-8979.
- ^ "Researchers find new phase of carbon, make diamond at room temperature". Retrieved Sep 22, 2019.
- ^ "Q-carbon is harder than diamond, incredibly simple to make | ExtremeTech". ExtremeTech. Retrieved Sep 22, 2019.
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- ISSN 2166-532X.
- ISSN 2166-3831.
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