Dichloro(cycloocta-1,5-diene)platinum(II)
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3D model (
JSmol ) |
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ChemSpider | |
ECHA InfoCard
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100.031.937 |
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
C8H12Cl2Pt | |
Molar mass | 374.17 g·mol−1 |
Melting point | 285 °C (545 °F; 558 K) |
Hazards | |
GHS labelling: | |
Warning | |
H315, H319, H335 | |
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Dichloro(1,5-cyclooctadiene)platinum(II) (Pt(cod)Cl2) is an
cycloocta-1,5-diene
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Dichloro(1,5-cyclooctadiene)platinum(II) is prepared by treating potassium tetrachloroplatinate with the diene:[1]
- K2PtCl4 + C8H12 → PtCl2C8H12 + 2 KCl
According to X-ray crystallography, the complex is square planar.[2][3]
See also
- Dichloro(1,5‐cyclooctadiene)palladium
References
- ISBN 978-0-470-13262-3.
- .
- .
Further reading
- J. L. Butikofer, E. W. Kalberer, W. C. Schuster, and D. M. Roddick, "The Crystal Structure of Dichloro(norbornadiene)platinum(II): A Comparison to Dichloro(cyclooctadiene)platinum(II)," Acta Crystallogr. C. 2004, m353-m354.